23301-82-8
23301-82-8 structure
- Name: Samarium,tris(1,1,1-trifluoro-2,4-pentanedionato-kO,kO')- (9CI)
- Chemical Name: samarium(3+),1,1,1-trifluoro-4-oxopent-2-en-2-olate
- CAS Number: 23301-82-8
- Molecular Formula: C15H15F9O6Sm
- Molecular Weight: 612.62200
- Create Date: 2018-07-14 07:45:25
- Modify Date: 2024-02-01 17:38:06
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| Name | samarium(3+),1,1,1-trifluoro-4-oxopent-2-en-2-olate |
|---|---|
| Synonyms |
Samarium(III) trifluoroacetylacetonate (REO)
SAMARIUM TRIFLUOROACETYLACETONATE Tris-(1,1,1-trifluoro-2,4-pentanedionato-O,O')-samarium SAMARIUM (III) TRIFLUOROACETYLACETONATE (-SM) (REO) SAMARIUM (III) TRIFLUOROACETYLACETONATE |
| Boiling Point | 106ºC at 760mmHg |
|---|---|
| Molecular Formula | C15H15F9O6Sm |
| Molecular Weight | 612.62200 |
| Flash Point | 26.1ºC |
| Exact Mass | 613.99200 |
| PSA | 102.42000 |
| LogP | 3.29070 |
| Vapour Pressure | 28.8mmHg at 25°C |
|
Section 1: Product Identification Chemical Name:Samarium (III) trifluoroacetylacetonate (99.9%-Sm) (REO) CAS Registry Number:23301-82-8 Formula:Sm(CF3COCHCOCH3)3 EINECS Number:none Chemical Family:metal fluorobeta-diketonate complexes Synonym:Bis(trifluoroacetylacetonate)samarium, Bis(1,1,1-trifluoro-2,4-pentandionato)samarium (III)
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound23301-82-8100%2.5mg/m3 (as F)2.5mg/m3 (as F) Section 3: Hazards Identification Emergency Overview:Irritating to skin, eyes and respiratory tract. Primary Routes of Exposure:Ingestion Eye Contact:Causes slight to mild irritation of the eyes Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:No information on the physiological effects of ingestion. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Product contains fluorine which under certain conditions of use, decomposition, or metabolism, may generate Chronic Health Affects:fluoride ion, causing, nausea, vomiting, labored breathing, hypocalcaemia, deterioration of bone and tooth structure, kidney and liver damage. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty in Inhalation: breathing, coughing, wheezing or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam. If this product is involved in a fire, firefighters should be equipped with NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes of hydrogen fluoride Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazard. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with powdered sodium carbonate or ground limestone and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a cool, dry place in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear appropriate chemical resistant gloves and protective clothing. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:white powder Molecular Weight:609.59 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:strong oxidizing agents Decomposition Products:carbon monoxide, samarium salts, hydrogen fluoride, carbonyl fluoride and organic fumes. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data available Mutagenic Effects:no data available Tetratogenic Effects:no data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Title compound not listed. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
| Hazard Codes | Xi: Irritant; |
|---|---|
| Risk Phrases | R36/37/38 |
| Safety Phrases | 26-36 |