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544-19-4

544-19-4 structure
544-19-4 structure

Name Formic acid, copper(2+) salt (1_1)
Synonyms Ameisensaeure,Kupfer(II)-formiat
coppper(II) formate
formic acid copper
Kupfer(II)-formiat-4-hydrat
formicacid,copper(2++)salt
formicacid,copper(2+)salt(1:1)
cupric formate
MFCD00167128
COPPER (II) FORMATE
cupricdiformate
copper diformate
formic acid,copper (II)-formate
COPPER FORMATE
Density 1.831 g/cm3
Boiling Point 100.6ºC at 760 mmHg
Melting Point 130ºC
Molecular Formula CH2CuO2++
Molecular Weight 109.57100
Flash Point 29.9ºC
Exact Mass 108.93500
PSA 37.30000
LogP 0.33420
Water Solubility 12.5g/100mL H2O [CRC10]; insoluble most organic solvents [MER06]

Section 1: Product Identification
Chemical Name:Copper (II) formate hydrate
CAS Registry Number:544-19-4
Formula:Cu(OOCH)2.XH2O
EINECS Number:none
Chemical Family:salt of an organic acid
Synonym:Formic acid, copper (+2) salt

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound544-19-4100%1mg/m3 (as Cu)1mg/m3 (as Cu)

Section 3: Hazards Identification
Emergency Overview:Irritating to the skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:The material is a fine powder. Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:Ingestion of copper compounds may lead to vomiting, exhaustion, anemia, convulsions and coma.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Handle the material in a ventilated area.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:green to blue pwdr.
Molecular Weight:153.55
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:1.831
Odor:none
Solubility in Water:slightly soluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable solid
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:Oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and copper salts.

SECTION 11: Toxicological Information
RTECS Data:No specific information available on this product.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):See Category Code N100 for reporting.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xn,N
Risk Phrases R20/21/22
Safety Phrases 22-36/37/39

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544-19-4 structure

544-19-4

Literature: Helvetica Chimica Acta, , vol. 17, p. 1094 - 1119

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544-19-4 structure

544-19-4

Literature: Helvetica Chimica Acta, , vol. 13, p. 978 - 1006

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544-19-4 structure

544-19-4

Literature: Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 24, p. 1202 - 1205 Zhurnal Neorganicheskoi Khimii, , vol. 24, p. 2172 - 2175

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544-19-4 structure

544-19-4

Literature: US2004/127751 A1, ; Page 4 ;

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544-19-4 structure

544-19-4

Literature: Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), , vol. 24, p. 213 - 216 Zhurnal Neorganicheskoi Khimii, , vol. 24, p. 384 - 388