Name | Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium |
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Synonyms |
Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium(II)
1,5-Cyclooctadiene MFCD07369035 |
Molecular Formula | C18H27ClRu |
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Molecular Weight | 379.93000 |
Exact Mass | 380.08400 |
LogP | 6.33430 |
Storage condition | 2-8℃ |
Section 1: Product Identification Chemical Name:Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium (II), 98% CAS Registry Number:92390-26-6 Formula:RuCl(C8H12)(C10H15) EINECS Number:none Chemical Family:organometallic complex Synonym:Chloro(pentamethylcyclopentadienyl)(1,5-cyclooctadiene)ruthenium
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound92390-26-6100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Ingestion, inhalation, skin, eyes Eye Contact:Causes irritation of the eyes. Skin Contact:Causes irritation of the skin. Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Chronic Health Affects:No information on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:none Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire, this material may emit toxic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store cold, in a tightly sealed container. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:brown microcrystals Molecular Weight:379.93 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:not determined Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air and moisture stable (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:none Incompatibility:oxidizing agents, halogens and active metals. Decomposition Products:carbon monoxide, carbon dioxide, organic fumes, phosphorous pentoxide and ruthenium oxide. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data Mutagenic Effects:No data Tetratogenic Effects:No data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
Symbol |
GHS02 |
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Signal Word | Danger |
Hazard Statements | H261 |
Precautionary Statements | P231 + P232-P422 |
Personal Protective Equipment | Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
Hazard Codes | Xi |
Risk Phrases | 20/21/22 |
Safety Phrases | 22-36/37/39 |
RIDADR | UN 3395 |
~92% 92390-26-6 |
Literature: Fagan, Paul J.; Mahoney, Wayne S.; Calabrese, Joseph C.; Williams, Ian D. Organometallics, 1990 , vol. 9, p. 1843 - 1852 |
~77% 92390-26-6 |
Literature: Bosch, H. William; Hund, Hans-Ulrich; Nietlispach, Daniel; Salzer, Albrecht Organometallics, 1992 , vol. 11, p. 2087 - 2098 |
~% 92390-26-6 |
Literature: Chemistry Letters, , p. 1161 - 1164 |
Precursor 2 | |
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DownStream 1 | |