Name | 6,6'-[[(1r,3r)-1,3-dimethyl-1,3-propanediyl]bis(oxy)]bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]dioxaphosphepin |
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Synonyms |
(R,R)-CHIRAPHITE
(2R,4R)-chirapite (2R,4R)-Chiraphite (2R,4R)-di[2,2'-(3,3'-di-tert-butyl-5,5'-dimethoxy-1,1-biphenyl)]-2,4-pentyldiphosphite |
Molecular Formula | C49H66O10P2 |
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Molecular Weight | 876.99000 |
Exact Mass | 876.41300 |
PSA | 107.94000 |
LogP | 14.84230 |
Section 1: Product Identification (+)-6,6'-{[(1R,3R)-1,3-Dimethyl-1,3-propanediyl]bis(oxy)}bis[4,8-bis(t-butyl)-2,10-dimethoxy-bibenzo[d,f][1,3,2]d Chemical Name: ioxaphosphepin], min. 95% (R,R)-Chiraphite CAS Registry Number:149646-83-3 Formula:C49H66O10P2 EINECS Number:none
Chemical Family:organophosphine ligand Synonym:(R,R)-Chiraphite Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title compound149646-83-3100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed. Primary Routes of Exposure:Inhalation, skin, eyes Eye Contact:Causes slight to mild irritation of the eyes. Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Dust is irritating to the nose, mucous membranes and respiratory tract. Ingestion:No specific information is available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with soap and water. Remove contaminated clothes if necessary. Seek medical Skin Exposure: assistance if irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:no data Autoignition Temperature:no data Explosion Limits:no data Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes, carbon monoxide and carbon dioxide. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage The material will degrade on prolonged exposure to air and moisture. Store and handle under an inert Handling and Storage: atmosphere of nitrogen or argon. Keep bottle tightly sealed and away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:off-white powder Molecular Weight:876.99 Melting Point:no data Boiling Point:no data Vapor Pressure:no data Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, moisture sensitive Hazardous Polymerization:No hazardous polymerization Conditions to Avoid:contact with air. This material may degrade on prolonged exposure to air. Incompatibility:strong oxidizing agents, air, moisture and halogens Decomposition Products:carbon monoxide, carbon dioxide, phosphorous pentoxide, organic fumes SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:no data Mutagenic Effects:no data Tetratogenic Effects:no data SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to federal, state and local regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory SARA (Title 313):Title compound not listed Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
~42% 149646-83-3 |
Literature: Buisman, Godfried J. H.; Vos, Eric J.; Kamer, Paul C. J.; Leeuwen, Piet W. N. M. van Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1995 , # 3 p. 409 - 418 |
~% 149646-83-3 |
Literature: Buisman, Godfried J. H.; Vos, Eric J.; Kamer, Paul C. J.; Leeuwen, Piet W. N. M. van Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1995 , # 3 p. 409 - 418 |
Precursor 3 | |
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DownStream 0 |