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27527-05-5

27527-05-5 structure
27527-05-5 structure

Name (2S)-2-amino-3-cyclohexylpropanoic acid
Synonyms (S)-(-)-α-Aminocyclohexanepropionic acid
(αS)-α-Aminocyclohexanepropanoic acid
L6TJ A1YZVQ &&L or S Form
(S)-3-Cyclohexylalanine
(S)-2-Amino-3-cyclohexylpropionic acid
(S)-2-amino-3-cyclohexanepropanoic acid
Cyclohexanepropanoic acid, α-amino-, (αS)-
(S)-α-Aminocyclohexanepropionic acid
(S)-2-amino-3-cyclohexylpropanoic acid
L-Cyclohexylalanine
3-Cyclohexyl-L-alanine
MFCD00190861
L-3-Cyclohexylalanine
Density 1.1±0.1 g/cm3
Boiling Point 307.1±25.0 °C at 760 mmHg
Melting Point 322 °C
Molecular Formula C9H17NO2
Molecular Weight 171.237
Flash Point 139.6±23.2 °C
Exact Mass 171.125931
PSA 63.32000
LogP 1.91
Vapour Pressure 0.0±1.4 mmHg at 25°C
Index of Refraction 1.498
Storage condition Store at 0°C
Name: 2-Amino-3-cyclohexylpropanoic acid tech Material Safety Data Sheet
Synonym: (S)-Cyclohexylalanin
CAS: 27527-05-5
Section 1 - Chemical Product MSDS Name:2-Amino-3-cyclohexylpropanoic acid tech Material Safety Data Sheet
Synonym:(S)-Cyclohexylalanin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
27527-05-5 2-Amino-3-cyclohexylpropanoic acid unlisted
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 27527-05-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 322 - 328 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H17NO2
Molecular Weight: 171

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 27527-05-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
2-Amino-3-cyclohexylpropanoic acid - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 27527-05-5: 0
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 27527-05-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 27527-05-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S22-S24/25-S37/39-S26
WGK Germany 3
HS Code 2922499990

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27527-05-5 structure

27527-05-5

Literature: Hoekstra, William J.; Sunder, Shyam S.; Cregge, Robert J.; Ashton, Louis A.; Stewart, Kenneth T.; King, Chi-Hsin R. Tetrahedron, 1992 , vol. 48, # 2 p. 307 - 318

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27527-05-5 structure

27527-05-5

Literature: Suarez, Rosa M.; Sestelo, Jose Perez; Sarandeses, Luis A. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 24 p. 3584 - 3587

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27527-05-5 structure

27527-05-5

Literature: Suarez, Rosa M.; Sestelo, Jose Perez; Sarandeses, Luis A. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 24 p. 3584 - 3587

~%

27527-05-5 structure

27527-05-5

Literature: Suarez, Rosa M.; Sestelo, Jose Perez; Sarandeses, Luis A. Organic and Biomolecular Chemistry, 2004 , vol. 2, # 24 p. 3584 - 3587

~%

27527-05-5 structure

27527-05-5

Literature: Axon, Jonathan R.; Beckwith, Athelstan L. J. Journal of the Chemical Society, Chemical Communications, 1995 , # 5 p. 549 - 550

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27527-05-5 structure

27527-05-5

Literature: Waser; Brauchli Helvetica Chimica Acta, 1923 , vol. 6, p. 205 Helvetica Chimica Acta, 1924 , vol. 7, p. 741,754 Full Text Show Details Waser; Brauchli Helvetica Chimica Acta, 1924 , vol. 7, p. 755
HS Code 2922499990
Summary HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%