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14364-93-3

14364-93-3 structure
14364-93-3 structure
  • Name: Iodo(trimethyl)platinum
  • Chemical Name: Iodotrimethylplatinum(IV)
  • CAS Number: 14364-93-3
  • Molecular Formula: C3H9IPt
  • Molecular Weight: 367.092
  • Create Date: 2018-04-18 08:00:00
  • Modify Date: 2024-01-09 17:25:35

Name Iodotrimethylplatinum(IV)
Synonyms carbanide,iodoplatinum
Platinum, iodotrimethyl-
Trimethylplatinum(IV) iodide
MFCD00013702
Iodo(trimethyl)platinum
Melting Point 250ºC (dec.)
Molecular Formula C3H9IPt
Molecular Weight 367.092
Exact Mass 366.939697

Section 1: Product Identification
Chemical Name:Iodotrimethylplatinum (IV), 99%
CAS Registry Number:14364-93-3
Formula:(CH3)3PtI
EINECS Number:None
Chemical Family:organometallic complexes
Synonym:Trimethylplatinum iodide

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound14364-93-3100%1mg/m3(as-Pt)no data

Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds has been shown to cause
Emergency Overview:
wheezing, coughing, and running of the nose. Skin contact can lead to dermatitis.
Primary Routes of Exposure:Ingestion, inhalation, skin
Eye Contact:Causes mild to moderate irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Irritating to the nose, mucous membranes and respiratory tract. Inhalation of the dust may cause wheezing,
Inhalation:
coughing, shortness of breath.
Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions.
Irritating to skin, eyes and respiratory tract. Exposure to platinum compounds may lead to wheezing, coughing,
Acute Health Affects:
and running of the nose. Skin exposure may lead to dermatitis.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self- contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic and corrosive fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, sodium carbonate or other suitable non combustible adsorbent and
Spill and Leak Procedures:
swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry place in a tightly sealed container.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:To minimize exposure, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:light orange xtl.
Molecular Weight:367.09
Melting Point:no data
Boiling Point:no data
Vapor Pressure:not applicable
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:oxidizing agents, halogens, and active metals
Decomposition Products:carbon monoxide, carbon dioxide, iodine, and platinum salts.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Not regulated by Title 313.
Second Ingredient:None


SECTION 16 - ADDITIONAL INFORMATION
N/A
Hazard Codes Xn
Risk Phrases 36/37/38
Safety Phrases 26-36/37/39

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Literature: Journal of the American Chemical Society, , vol. 60, p. 3085

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14364-93-3

Literature: Journal of the American Chemical Society, , vol. 75, p. 2064

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Literature: Journal of the Chemical Society, , vol. 95, p. 572 Proceedings of the Chemical Society, London, , vol. 23, p. 87

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14364-93-3

Literature: Chatt, J. in: Plesch, P. H., Cationic polymerisation and related complexes, Cambridge 1953, S. 50

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14364-93-3

Literature: Doklady, , vol. 57, p. 259 - 261