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300-76-5

300-76-5 structure
300-76-5 structure
Name naled
Synonyms BRP
phosphatedeo,o-dimethyleetdeo-(1,2-dibromo-2,2-dichlorethyle)(french)
thodibrom
DIBROM (NALED)
o-Dibrom 8E
1,2-Dibromo-2,2-dichloroethyl dimethyl phosphatic acid
(1,2-Dibromo-2,2-dichloroethyl) dimethyl phosphate,Bromchlophos,Naled
fosforano-1,2-dwubromo-2,2-dwuchloroetylo-o,o-dwumetylowy
1,2-dibromo-2,2-dichloro-ethyl dimethyl phosphate
Arthodibrom
MFCD00053227
Orthodibromo
Dibromfos
BROMCHLOPHOS
Bromex
Naled dibromo
Naled Solution, 100ppm
DIBROM
Trumpet
Bromex 50
phosphoricacid,1,2-dibromo-2,2-dichloroethyldimethylester
Dimethyl 1,2-dibromo-2,2-dichloroethyl phosphate
o,o-dimethylo-2,2-dichloro-1,2-dibromoethylphosphate
orthodibrom
o-(1,2-dibromo-2,2-dicloro-etil)-o,o-dimetil-fosfato
BROMEX
Dibrom
Ortho Dibrom 8E
orthodibromo
bromochlorphos
dimethyl1,2-dibromo-2,2-dichloroethylphosphate
NALED
flibolex
nikabrom
RE-4355
fosforan
o,2,2-dichloro-1,2-dibromoethylphosphate
Fosbrom
1,2-DIBROMO-2,2-DICHLOROETHYL DIMETHYL-PHOSPHATE
oms75
hibrom
naled,[liquid]
naledu
EINECS 206-098-3
(RS)-1,2-dibromo-2,2-dichloroethyl dimethyl phosphate
fosbrom
dimethyl-1,2-dibromo-2,2-dichloroethylphosphate
rac-(1R)-1,2-dibromo-2,2-dichloroethyl dimethyl phosphate
phosphatedeo,o-dimethyleetdeo-(1,2-dibromo-2,2-dichlorethyle)
1,2-dibromo-2,2-dichloro-ethanodimethylphosphate
1,2-DIBROMO-2,2-DICHLOROETHYLDIMETHYLESTERPHOSPHATE
Phosphoric acid 1,2-dibromo-2,2-dichloroethyl dimethyl ester
O-(1,2-dibromo-2,2-dichloethyl )-0,0-dimethylphosphate
o,o-dimethyl-o-(1,2-dibromo-2,2-dichloroethyl)phosphate
Naled 250mg [-5]
(1,2-Dibromo-2,2-dichloroethyl) dimethyl phosphate, Bromchlophos, Naled
o-(1,2-dibroom-2,2-dichloor-ethyl)-o,o-dimethyl-fosfaat
o-(1,2-dibrom-2,2-dichlor-aethyl)-o,o-dimethyl-phosphat
bromex(insecticide)
ent24988
ortho4355
Alvora
naled (bsi,iso,ansi,esa)
1,2-Dibromo-2,2-dichloroethyl dimethyl phosphate
o,o-dimethyl-o-(1,2-dibrom-2,2-dichlor-aethyl)-phosphat
bromex50
Phosphoric acid, 1,2-dibromo-2,2-dichloroethyl dimethyl ester
Ortho-Dibrom
phosphoric acid 1,2-dibromo-2,2-dichloro-ethyl ester dimethyl ester
DIMETHYL-1,2-DIBROMO-2-DICHLOROETHYL-PHOSPHATE
O,O'-DIMETHYL-1,2-DIBROMO-2,2-DICHLOROETHYL PHOSPHATE
naled (ISO) 1,2-dibromo-2,2-dichloroethyl dimethyl phosphate
(1,2-dibromo-2,2-dichloroethyl) dimethyl phosphate
Density 2.0±0.1 g/cm3
Boiling Point 273.8±40.0 °C at 760 mmHg
Melting Point 26.5-27.5ºC
Molecular Formula C4H7Br2Cl2O4P
Molecular Weight 380.784
Flash Point 119.4±27.3 °C
Exact Mass 377.782562
PSA 54.57000
LogP 1.86
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.529
Storage condition 0-6°C

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TB9450000
CHEMICAL NAME :
Phosphoric acid, 1,2-dibromo-2,2-dichloroethyl dimethyl ester
CAS REGISTRY NUMBER :
300-76-5
LAST UPDATED :
199712
DATA ITEMS CITED :
43
MOLECULAR FORMULA :
C4-H7-Br2-Cl2-O4-P
MOLECULAR WEIGHT :
380.80
WISWESSER LINE NOTATION :
GXGEYEOPO&O1&O1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Open irritation test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Human - man
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
92 mg/kg
TOXIC EFFECTS :
Behavioral - tremor Gastrointestinal - changes in structure or function of salivary glands Gastrointestinal - hypermotility, diarrhea
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
800 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
35 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
222 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - effect, not otherwise specified Behavioral - convulsions or effect on seizure threshold Gastrointestinal - changes in structure or function of salivary glands
TYPE OF TEST :
LC - Lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>1500 mg/m3/6H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
84 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1100 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
52 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
430 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1350 mg/kg/9W-I
TOXIC EFFECTS :
Nutritional and Gross Metabolic - body temperature decrease Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - true cholinesterase Related to Chronic Data - death

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Bacillus subtilis
REFERENCE :
JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 29,268,1981 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 3 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW DTTIAF Deutsche Tieraerztliche Wochenschrift. (Hanover, Fed. Rep. Ger.) V.1-77, 1893-1970. Volume(issue)/page/year: 80,485,1973 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 MSHA STANDARD-air:TWA 3 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,73,1971 OSHA PEL (Gen Indu):8H TWA 3 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 3 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 3 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 3 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 3 mg/m3;Skin JAN 1993 OEL-AUSTRIA:TWA 3 mg/m3 JAN 1993 OEL-BELGIUM:TWA 3 mg/m3;Skin JAN 1993 OEL-DENMARK:TWA 3 mg/m3 JAN 1993 OEL-FINLAND:TWA 3 mg/m3;STEL 6 mg/m3 JAN 1993 OEL-FRANCE:TWA 3 mg/m3;Skin JAN 1993 OEL-GERMANY:TWA 3 mg/m3;Carcinogen JAN 1993 OEL-THE NETHERLANDS:TWA 3 mg/m3 JAN 1993 OEL-RUSSIA:STEL 0.5 mg/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 3 mg/m3 JAN 1993 OEL-THAILAND:TWA 3 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 3 mg/m3;STEL 6 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO THE CHEMICAL-air:10H TWA 3 mg/m3 (Sk) REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 26420 No. of Facilities: 16 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 16 (estimated)
Symbol GHS06 GHS09
GHS06, GHS09
Signal Word Danger
Hazard Statements H301-H312-H315-H319-H400
Precautionary Statements P273-P301 + P310 + P330-P302 + P352 + P312-P305 + P351 + P338-P337 + P313-P391
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xn,N,T
Risk Phrases R21/22
Safety Phrases 36/37-61
RIDADR 3018
WGK Germany 3
RTECS TB9450000
Packaging Group I
HS Code 2919900090
HS Code 2919900090
Summary 2919900090 other phosphoric esters and their salts, including lactophosphates; their halogenated, sulphonated, nitrated or nitrosated derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%
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