2176-98-9

Synonym:Tin, tetrapropyl-, Tetrapropylstannane

---

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound2176-98-9100%0.1mg/m30.1mg/m3

---

Section 3: Hazards Identification
Emergency Overview:Irritating to the respiratory tract, skin and eyes. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:Causes severe irritation of the eyes.
Causes slight to mild irritation of the skin. Prolonged contact may dry the skin and lead to rashes or more
Skin Contact:
severe irritation.
Inhalation:Irritating to skin, eyes and respiratory tract.
Delayed and permanent psycho-neurological disturbances; impairment of vision, unsteadiness, nausea and
Ingestion:
vomiting.
Irritating to skin, eyes and mucous membranes. Ingestion of certain organotin compounds may cause delayed
Acute Health Affects:
poisoning (4 days) with cerebral edema causing damage to the central nervous system.
Repeated exposure to certain organic tin compounds may cause problems with vision, skin, respiratory
Chronic Health Affects:
system, central nervous system, liver, kidneys, urinary tract, and blood.
NTP:No
IARC:No
OSHA:No

---

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

---

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, foam or dry powder
Fire fighters should be equipped with a NIOSH approved positive pressure self-contained breathing apparatus
Special Fire Fighting Procedures:
and full protective clothing.
Hazardous Combustion andcarbon monoxide, carbon dioxide, soot, organic fumes and tin compounds.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

---

SECTION 6: Accidental Release Measures
Small spills can be mixed with vermiculite, ground limestone, sodium carbonate or other suitable
Spill and Leak Procedures:
noncombustible adsorbent and swept up.

---

SECTION 7: Handling and Storage
Handling and Storage:Store in a cool, dry, well ventilated area away from heat and direct sunlight. Keep containers tightly sealed.

---

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Work with this product in a well-ventilated area, preferably a fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Work with this product in a well-ventilated area, preferably a fume hood.
Additional Protection:No additional protection required.

---

SECTION 9: Physical and Chemical Properties
Color and Form:colorless liq.
Molecular Weight:291.05
Melting Point:no data
Boiling Point:222°C
Vapor Pressure:no data
Specific Gravity:1.1065(20°)
Odor:not determined
Solubility in Water:insoluble

---

SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:strong oxidizing agents and halogens
Decomposition Products:carbon monoxide, carbon dioxide, tin oxide, and organic fumes.

---

SECTION 11: Toxicological Information
RTECS Data:Parenteral (mouse); LDLo: 73 mg/kg.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

---

SECTION 12: Ecological Information
Ecological Information:No information available

---

SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

---

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

---

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none

---

SECTION 16 - ADDITIONAL INFORMATION
N/A

DATA ITEMS CITED :

1

MOLECULAR FORMULA :

C12-H28-Sn

MOLECULAR WEIGHT :

291.09

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :

LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :

Parenteral

SPECIES OBSERVED :

Rodent - mouse

DOSE/DURATION :

73 mg/kg

TOXIC EFFECTS :

Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage)

REFERENCE :

COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. (Paris, France) V.1-261, 1835-1965. For publisher information, see CRASEV. Volume(issue)/page/year: 239,1091,1954