2-bromo-6-methyl-4-nitroaniline structure
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Common Name | 2-bromo-6-methyl-4-nitroaniline | ||
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CAS Number | 102170-56-9 | Molecular Weight | 231.04700 | |
Density | 1.698 g/cm3 | Boiling Point | 366ºC at 760 mmHg | |
Molecular Formula | C7H7BrN2O2 | Melting Point | 180-184ºC | |
MSDS | Chinese USA | Flash Point | 175.2ºC |
Name | 2-bromo-6-methyl-4-nitroaniline |
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Synonym | More Synonyms |
Density | 1.698 g/cm3 |
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Boiling Point | 366ºC at 760 mmHg |
Melting Point | 180-184ºC |
Molecular Formula | C7H7BrN2O2 |
Molecular Weight | 231.04700 |
Flash Point | 175.2ºC |
Exact Mass | 229.96900 |
PSA | 71.84000 |
LogP | 3.35230 |
Vapour Pressure | 1.51E-05mmHg at 25°C |
Index of Refraction | 1.648 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 20/21/22 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed. Potential Health Effects Eye: May cause eye irritation. Skin: May cause skin irritation. Harmful if absorbed through the skin. Ingestion: Harmful if swallowed. May cause irritation of the digestive tract. Inhalation: Harmful if inhaled. May cause respiratory tract irritation. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 102170-56-9: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: off-white Odor: Not available. pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 180-181 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C7H7BrN2O2 Molecular Weight: 231.05 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide, hydrogen bromide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 102170-56-9 unlisted. LD50/LC50: Not available. Carcinogenicity: 2-Bromo-6-methyl-4-nitroaniline - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XN Risk Phrases: R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 102170-56-9: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 102170-56-9 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 102170-56-9 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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Hazard Codes | Xi: Irritant; |
Risk Phrases | R20/21/22 |
Safety Phrases | S36/37 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
HS Code | 2921430090 |
~91% 2-bromo-6-methy... CAS#:102170-56-9 |
Literature: Kajigaeshi, Shoji; Kakinami, Takaaki; Inoue, Kazuhisa; Kondo, Manabu; Nakamura, Hiroko; et al. Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 2 p. 597 - 599 |
~84% 2-bromo-6-methy... CAS#:102170-56-9 |
Literature: O'Neill, Paul M.; Willock, David J.; Hawley, Shaun R.; Bray, Patrick G.; Storr, Richard C.; Ward, Stephen A.; Park, B. Kevin Journal of Medicinal Chemistry, 1997 , vol. 40, # 4 p. 437 - 448 |
~% 2-bromo-6-methy... CAS#:102170-56-9 |
Literature: Bulletin de la Societe Chimique de France, , vol. <4>35, p. 1328 |
HS Code | 2921430090 |
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Summary | HS:2921430090 toluidines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
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