Methyl (2R)-3-bromo-2-methylpropanoate

Modify Date: 2024-01-07 18:32:30

Methyl (2R)-3-bromo-2-methylpropanoate Structure
Methyl (2R)-3-bromo-2-methylpropanoate structure
Common Name Methyl (2R)-3-bromo-2-methylpropanoate
CAS Number 110556-33-7 Molecular Weight 181.028
Density 1.4±0.1 g/cm3 Boiling Point 173.7±0.0 °C at 760 mmHg
Molecular Formula C5H9BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 73.9±0.0 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name methyl (r)-(+)-3-bromo-2-methylpropionate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 173.7±0.0 °C at 760 mmHg
Molecular Formula C5H9BrO2
Molecular Weight 181.028
Flash Point 73.9±0.0 °C
Exact Mass 179.978592
PSA 26.30000
LogP 1.50
Vapour Pressure 1.3±0.3 mmHg at 25°C
Index of Refraction 1.454

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
HS Code 2915900090

 Synthetic Route

~74%

Methyl (2R)-3-bromo-2-methylpropanoate Structure

Methyl (2R)-3-b...

CAS#:110556-33-7

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 2.2 p. 364 - 369 Zhurnal Organicheskoi Khimii, , vol. 26, # 2 p. 425 - 432

~79%

Methyl (2R)-3-bromo-2-methylpropanoate Structure

Methyl (2R)-3-b...

CAS#:110556-33-7

Literature: Tetrahedron Asymmetry, , vol. 9, # 7 p. 1131 - 1135

~68%

Methyl (2R)-3-bromo-2-methylpropanoate Structure

Methyl (2R)-3-b...

CAS#:110556-33-7

Literature: Tetrahedron Letters, , vol. 28, # 3 p. 337 - 340

~%

Methyl (2R)-3-bromo-2-methylpropanoate Structure

Methyl (2R)-3-b...

CAS#:110556-33-7

Literature: Advanced Synthesis and Catalysis, , vol. 354, # 8 p. 1519 - 1528

~%

Methyl (2R)-3-bromo-2-methylpropanoate Structure

Methyl (2R)-3-b...

CAS#:110556-33-7

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 2.2 p. 364 - 369 Zhurnal Organicheskoi Khimii, , vol. 26, # 2 p. 425 - 432

~%

Methyl (2R)-3-bromo-2-methylpropanoate Structure

Methyl (2R)-3-b...

CAS#:110556-33-7

Literature: Angewandte Chemie - International Edition, , vol. 49, # 35 p. 6111 - 6115

~%

Methyl (2R)-3-bromo-2-methylpropanoate Structure

Methyl (2R)-3-b...

CAS#:110556-33-7

Literature: Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 37, # 11 p. 2387 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 11 p. 2647 - 2648

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Synonyms

(R)-(+)-3-Bromo-2-Methylpropionic Acid Methyl Ester
(R)-(+)-3-Bromoisobutyric Acid Methyl Ester
MFCD00010639
Methyl (R)-(+)-3-BroMoisobutyrate
METHYL (R)-(+)-3-BROMO-2-METHYLPROPIONATE
Methyl (2R)-3-bromo-2-methylpropanoate
Propanoic acid, 3-bromo-2-methyl-, methyl ester, (2R)-