[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE

Modify Date: 2024-01-15 09:40:21

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE Structure
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE structure
Common Name [(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE
CAS Number 115826-95-4 Molecular Weight 799.998
Density N/A Boiling Point 147 °C18 mm Hg(lit.)
Molecular Formula C44H32Cl2P2Pd Melting Point 106-108 °C(lit.)
MSDS Chinese USA Flash Point 146-148°C/18mm
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name [(R)-(+)-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) chloride
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 147 °C18 mm Hg(lit.)
Melting Point 106-108 °C(lit.)
Molecular Formula C44H32Cl2P2Pd
Molecular Weight 799.998
Flash Point 146-148°C/18mm
Exact Mass 798.039124
PSA 27.18000
LogP 10.55540
Vapour Pressure 5.55E-20mmHg at 25°C
Water Solubility soluble

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H312-H315-H319-H332-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn: Harmful;
Risk Phrases R20/21/22
Safety Phrases S26-S37/39
RIDADR NONH for all modes of transport
WGK Germany 3

 Synthetic Route

~97%

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE Structure

[(R)-(+)-2,2'-B...

CAS#:115826-95-4

Literature: BRISTOL-MYERS SQUIBB COMPANY Patent: WO2006/138373 A2, 2006 ; Location in patent: Page/Page column 98 ; WO 2006/138373 A2

~99%

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE Structure

[(R)-(+)-2,2'-B...

CAS#:115826-95-4

Literature: Veron, Anna C.; Felber, Michael; Blacque, Olivier; Spingler, Bernhard Polyhedron, 2013 , vol. 52, p. 102 - 105

~77%

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE Structure

[(R)-(+)-2,2'-B...

CAS#:115826-95-4

Literature: Ozawa, Fumiyuki; Kubo, Akihiko; Matsumoto, Yonetatsu; Hayashi, Tamio; Nishioka, Eriko; et al. Organometallics, 1993 , vol. 12, p. 4188 - 4196

 Precursor & DownStream

Precursor  2

DownStream  0

 Synonyms

MFCD00075254
[(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride
1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine) - dichloropalladium (1:1)
[(R)-(+)-2,2-Bis(Diphenylphosphino)-1,1-binaphthyl]palladium(II)chloride
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE