Platinate(1-),trichloro(h2-ethene)-, potassium (1:1)

Modify Date: 2024-01-13 17:04:07

Platinate(1-),trichloro(h2-ethene)-, potassium (1:1) Structure
Platinate(1-),trichloro(h2-ethene)-, potassium (1:1) structure
Common Name Platinate(1-),trichloro(h2-ethene)-, potassium (1:1)
CAS Number 12012-50-9 Molecular Weight 464.80000
Density N/A Boiling Point N/A
Molecular Formula C2H6Cl3K3OPt Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name potassium,ethene,platinum(2+),trichloride
Synonym More Synonyms

 Chemical & Physical Properties

Molecular Formula C2H6Cl3K3OPt
Molecular Weight 464.80000
Exact Mass 462.80400
PSA 9.23000
LogP 2.92330

 MSDS

Name: Potassium trichloro(ethylene)platinate(ii) monohydrate Material Safety Data Sheet
Synonym: Zeise's sal
CAS: 12012-50-9
Section 1 - Chemical Product MSDS Name:Potassium trichloro(ethylene)platinate(ii) monohydrate Material Safety Data Sheet
Synonym:Zeise's sal

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
12012-50-9 Potassium trichloro(ethylene)platinate 234-577-7
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air).
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower.
Exposure Limits CAS# 12012-50-9: United States OSHA: 0.002 mg/m3 TWA (as Pt) (listed under Platin soluble salts).
Belgium - TWA: (listed as platinum soluble salts): 0.002 mg/m3 VL (as Pt) Japan: (listed as platinum soluble salts): 0.001 mg/m3 OEL (as Pt Malaysia: (listed as platinum soluble salts): 0.002 mg/m3 TWA (as Netherlands: (listed as platinum soluble salts): 0.002 mg/m3 MAC Pt) Personal Protective Equipment Eyes: Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear a chemical apron.
Respirators:
A NIOSH/MSHA approved air purifying dust or mist respirator or European Standard EN 149.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: yellow-green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 220 deg C dec
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C2H4Cl3KPt.H2O
Molecular Weight: 386.60

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 12012-50-9: TP1880000 LD50/LC50:
Not available.
Carcinogenicity:
Potassium trichloro(ethylene)platinate(II) monohydrate - Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 12012-50-9: No information available.
Canada
CAS# 12012-50-9 is listed on Canada's NDSL List.
CAS# 12012-50-9 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 12012-50-9 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TP1880000
CHEMICAL NAME :
Platinate(1-), trichloroethylene-, dipotassium
CAS REGISTRY NUMBER :
12012-50-9
LAST UPDATED :
199712
DATA ITEMS CITED :
21
MOLECULAR FORMULA :
C2-H4-Cl3-Pt.K
MOLECULAR WEIGHT :
368.60
WISWESSER LINE NOTATION :
G-PT-GG1U1 &-KA- 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
85 mg/kg
TOXIC EFFECTS :
Tumorigenic - active as anti-cancer agent
REFERENCE :
VOONAW Voprosy Onkologii. Problems of Oncology. For English translation, see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-10, 1928-37; V.1- 1955- Volume(issue)/page/year: 25(11),47,1979 *** REVIEWS *** ACGIH TLV-TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.002 mg(Pt)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,213,1971 OSHA PEL (Gen Indu):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.002 mg(Pt)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.002 mg(Pt)/m3 (dust) JAN 1993 OEL-AUSTRALIA:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-BELGIUM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-DENMARK:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-FINLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-GERMANY:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-HUNGARY:STEL 0.002 mg(Pt)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.002 mg(Pt)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

 Safety Information

Risk Phrases 36/37/38

 Synthetic Route

~87%

Platinate(1-),trichloro(h2-ethene)-, potassium (1:1) Structure

Platinate(1-),t...

CAS#:12012-50-9

Literature: Shoemaker, Krista A.; Leadbeater, Nicholas E. Inorganic Chemistry Communications, 2009 , vol. 12, # 5 p. 341 - 342

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Platinate(1-),trichloro(h2-ethene)-, potassium (1:1) Structure

Platinate(1-),t...

CAS#:12012-50-9

Literature: Gmelin Handbook: Pt: MVol.D, 194, page 428 - 431

 Synonyms

Platinate(1-),trichloroethylene-,dipotassium
Platinate(1-),trichloro(ethylene)-,potassium
potassium trichloro(ethene)platinate(II)
Potassium trichloroethyleneplatinate
Potassium trichloro(ethylene)platinate(II)
Platinate(1-),trichloro(eta2-ethene)-,potassium
Potassium ethylenetrichloroplatinate(II)
Pt-93
Zeise-salt
EINECS 234-577-7
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