allyl-chloro-palladium

Modify Date: 2024-01-02 17:34:00

allyl-chloro-palladium Structure
allyl-chloro-palladium structure
Common Name allyl-chloro-palladium
CAS Number 12012-95-2 Molecular Weight 365.890
Density N/A Boiling Point N/A
Molecular Formula C6H10Cl2Pd2 Melting Point 120°C (dec.)
MSDS Chinese USA Flash Point N/A
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name Allylpalladium chloride dimer
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point 120°C (dec.)
Molecular Formula C6H10Cl2Pd2
Molecular Weight 365.890
Exact Mass 363.822937
LogP 3.65900
Vapour Pressure 8480mmHg at 25°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
RT3510000
CHEMICAL NAME :
Palladium chloride, allyl- (Dimer)
CAS REGISTRY NUMBER :
12012-95-2
LAST UPDATED :
197901
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C6-H10-Cl2-Pd2
MOLECULAR WEIGHT :
365.86
WISWESSER LINE NOTATION :
2U1-PD-G 2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
AEHLAU Archives of Environmental Health. (Heldref Pub., 4000 Albemarle St., NW, Washington, DC 20016) V.1- 1960- Volume(issue)/page/year: 30,168,1975

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P280-P304 + P340 + P312-P305 + P351 + P338-P337 + P313
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Faceshields;Gloves
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases 26-36
RIDADR UN 3278
WGK Germany 3
RTECS RT3510000
Packaging Group I
Hazard Class 6.1(a)
HS Code 28439090

 Precursor & DownStream

Precursor  0

DownStream  1

 Customs

HS Code 28439090

 Articles15

More Articles
Room-temperature Stille cross-couplings of alkenyltin reagents and functionalized alkyl bromides that possess beta hydrogens.

J. Am. Chem. Soc. 125 , 3718, (2003)

This communication describes a significant expansion in the scope of Stille reactions of Csp3-X electrophiles, specifically, that Pd/P(t-Bu)2Me catalyzes the room-temperature cross-coupling of a varie...

The first applications of carbene ligands in cross-couplings of alkyl electrophiles: sonogashira reactions of unactivated alkyl bromides and iodides.

J. Am. Chem. Soc. 125 , 13642, (2003)

A Pd/N-heterocyclic carbene-based catalyst achieves the Sonogashira coupling of an array of functionalized, beta-hydrogen-containing alkyl bromides and iodides under mild conditions. By furnishing the...

Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions.

J. Am. Chem. Soc. 123 , 4366, (2001)

 Synonyms

chloropalladium(1+),prop-1-ene
MFCD00044874
Bis(allylchloropalladium)
[PdCl(allyl)]2
EINECS 234-579-8
Bis(allyl)dichlorodipalladium
Diallyldichlorodipalladium
Allylpalladium(II) Chloride Dimer
[PdCl(C3H5)]2
Bis(allyl)dichloropalladium
Di-μ-chlorobis[(η-allyl)palladium(II)]
Allylchloropalladium dimer
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