(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)

Modify Date: 2024-01-14 16:20:20

(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) structure	Common Name	(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
	CAS Number	12245-39-5	Molecular Weight	310.194
	Density	N/A	Boiling Point	153.5ºC at 760mmHg
	Molecular Formula	C₁₃H₁₉O₂Rh	Melting Point	138-140ºC(lit.)
	MSDS	Chinese USA	Flash Point	31.7ºC
	Symbol	GHS07	Signal Word	Warning

Name	acetylacetonato(1,5-cyclooctadiene)rhodium(i)
Synonym	More Synonyms

Boiling Point	153.5ºC at 760mmHg
Melting Point	138-140ºC(lit.)
Molecular Formula	C₁₃H₁₉O₂Rh
Molecular Weight	310.194
Flash Point	31.7ºC
Exact Mass	310.044006
PSA	26.30000
LogP	3.63290
Vapour Pressure	4.25mmHg at 25°C
Storage condition	below 5° C

MSDS(Chinese)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: VI9292000

CHEMICAL NAME :: Rhodium, (1,5-cyclooctadiene)(2,4-pentanedionato)-

CAS REGISTRY NUMBER :: 12245-39-5

LAST UPDATED :: 199712

DATA ITEMS CITED :: 24

MOLECULAR FORMULA :: C13-H19-O2-Rh

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 34 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 45,1,1983 *** REVIEWS *** ACGIH TLV-TWA 1 mg(Rh)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg(Rh)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,222,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Rh)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 mg(Rh)/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg(Rh)/m3 JAN 1993 OEL-DENMARK:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-DENMARK:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-FINLAND:TWA 0.001 mg(Rh)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-FRANCE:TWA 1 mg(Rh)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.001 mg(Rh)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Rh)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.001 mg(Rh)/m3;STEL 0.003 mg(Rh)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Rh)/m3;STEL 0.3 mg(Rh)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes	Xi: Irritant;
Risk Phrases	R36/37/38
Safety Phrases	26-37/39
RIDADR	NONH for all modes of transport
WGK Germany	3
RTECS	VI9292000

Antitumor effects of rhodium(I), iridium(I) and ruthenium(II) complexes in comparison with cis-dichlorodiammino platinum(II) in mice bearing Lewis lung carcinoma.

Chem. Biol. Interact. 45(1) , 1-6, (1983)

The effects of square planar rhodium, [RhacacCOD]o and iridium, [IracacCOD]o complexes and of octahedral ruthenium, [cis-RuCl2 (DMSO)4]o complex have been examined in comparison with cis-dichlorodiamm...

(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu

(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)

(1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate

acetylacetonate-1,5-cyclooctadienerhodium

MFCD00075046

Rh(acac)(COD)

[4-(Hydroxy-κO)-3-penten-2-onato]rhodium - (1Z,5Z)-1,5-cyclooctadiene (1:1)

Acetylacetonato(1,5

RHODIUM (1,5-CYCLOOCTADIENE)-2,4-PENTANEDIONATE

(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium

Rhodium, [4-(hydroxy-κO)-3-penten-2-onato]-, compd. with (1Z,5Z)-1,5-cyclooctadiene (1:1)