Propan-2-one oxime

Modify Date: 2024-01-02 14:19:21

Propan-2-one oxime Structure
Propan-2-one oxime structure
 Common Name Propan-2-one oxime
CAS Number 127-06-0 Molecular Weight 73.094
Density 0.9±0.1 g/cm3 Boiling Point 135.0±0.0 °C at 760 mmHg
Molecular Formula C3H7NO Melting Point 60-63 °C(lit.)
MSDS Chinese USA Flash Point 45.2±8.0 °C

 Names

Name acetone oxime
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 135.0±0.0 °C at 760 mmHg
Melting Point 60-63 °C(lit.)
Molecular Formula C3H7NO
Molecular Weight 73.094
Flash Point 45.2±8.0 °C
Exact Mass 73.052765
PSA 32.59000
LogP 0.12
Vapour Pressure 4.7±0.5 mmHg at 25°C
Index of Refraction 1.410
Water Solubility 330 g/L (20 ºC)

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AL6825000
CHEMICAL NAME :
Acetone, oxime
CAS REGISTRY NUMBER :
127-06-0
BEILSTEIN REFERENCE NO. :
1560146
LAST UPDATED :
199712
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C3-H7-N-O
MOLECULAR WEIGHT :
73.11
WISWESSER LINE NOTATION :
QNUY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,26,1953
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4 gm/kg
TOXIC EFFECTS :
Behavioral - coma
REFERENCE :
JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 119,522,1957
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>3 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 12,227,1978

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes Xn:Harmful;
Safety Phrases S22-S24/25
RIDADR UN1325
WGK Germany 3
RTECS AL6825000
Packaging Group III
Hazard Class 4.1
HS Code 2928000090

 Synthetic Route

 Customs

HS Code 2928000090
Summary 2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Articles14

More Articles
Slow oxidation of acetoxime and methylethyl ketoxime to the corresponding nitronates and hydroxy nitronates by liver microsomes from rats, mice, and humans.

Toxicol. Sci. 47(2) , 144-50, (1999)

Acetoxime and methylethyl ketoxime (MEKO) are tumorigenic in rodents, inducing liver tumors in male animals. The mechanisms of tumorigenicity for these compounds are not well defined. Oxidation of the...

Synthesis and anticancer evaluation of benzyloxyurea derivatives.

Chem. Pharm. Bull. 62(9) , 898-905, (2014)

A series of novel benzyloxyurea derivatives was designed, synthesized by substituting different benzyls or phenyls on N,N'-positions of the hydroxyurea (HU). These target compounds were evaluated for ...

Reversion of structure-activity relationships of antitumor platinum complexes by acetoxime but not hydroxylamine ligands.

Mol. Pharmacol. 71(1) , 357-65, (2007)

The presence of cis-configured exchangeable ligands has long been considered a prerequisite for antitumor activity of platinum complexes, but over the past few years, several examples violating this s...

 Synonyms

N-Hydroxypropan-2-imine
Acetone, oxime
β-Isonitrosopropane
MFCD00002118
Acetone oxime
2-Propanone, oxime
Acetoxime
EINECS 204-820-1
b-Isonitrosopropane
N-Hydroxy-2-propanimine
N-propan-2-ylidenehydroxylamine
propan-2-one oxime
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