Phosphorus pentasulfide

Modify Date: 2024-01-05 10:19:51

Phosphorus pentasulfide Structure
Phosphorus pentasulfide structure
Common Name Phosphorus pentasulfide
CAS Number 1314-80-3 Molecular Weight 444.545
Density 2.3±0.1 g/cm3 Boiling Point 514°C
Molecular Formula P4S10 Melting Point 286 °C
MSDS Chinese USA Flash Point N/A
Symbol GHS02 GHS07 GHS09
GHS02, GHS07, GHS09
Signal Word Danger

 Names

Name Phosphorus pentasulfide
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.3±0.1 g/cm3
Boiling Point 514°C
Melting Point 286 °C
Molecular Formula P4S10
Molecular Weight 444.545
Exact Mass 443.615753
PSA 221.94000
LogP 4.96340
Index of Refraction 2.029
Water Solubility reacts

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TH4375000
CHEMICAL NAME :
Phosphorus sulfide
CAS REGISTRY NUMBER :
1314-80-3
LAST UPDATED :
199712
DATA ITEMS CITED :
31
MOLECULAR FORMULA :
P2-S5
MOLECULAR WEIGHT :
222.24
WISWESSER LINE NOTATION :
P4 S7

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
389 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972 Volume(issue)/page/year: -,16,1972
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
3160 mg/kg
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0571217 *** REVIEWS *** ACGIH TLV-STEL 3 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 1 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,211,1971 OSHA PEL (Gen Indu):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 1 mg/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL-BELGIUM:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL-DENMARK:TWA 1 mg/m3 JAN 1993 OEL-FINLAND:STEL 1 mg/m3 JAN 1993 OEL-FRANCE:TWA 1 mg/m3 JAN 1993 OEL-GERMANY:TWA 1 mg/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 1 mg/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 1 mg/m3 JAN 1993 OEL-SWITZERLAND:TWA 1 mg/m3;STEL 2 mg/m3 JAN 1993 OEL-THAILAND:TWA 1 mg/m3 JAN 1993 OEL-TURKEY:TWA 1 mg/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 1 mg/m3;STEL 3 mg/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO PHOSPHORUS PENTASULFIDE-air:TWA 1 mg/m3;STEL 3 mg/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 59162 No. of Facilities: 31 (estimated) No. of Industries: 1 No. of Occupations: 14 No. of Employees: 1092 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 59162 No. of Facilities: 94 (estimated) No. of Industries: 4 No. of Occupations: 7 No. of Employees: 5372 (estimated) No. of Female Employees: 446 (estimated)

 Safety Information

Symbol GHS02 GHS07 GHS09
GHS02, GHS07, GHS09
Signal Word Danger
Hazard Statements H228-H260-H302-H332-H400
Supplemental HS Contact with water liberates toxic gas.
Precautionary Statements P210-P223-P231 + P232-P273-P370 + P378-P422
Hazard Codes F:Flammable;Xn:Harmful;N:Dangerousfortheenvironment;
Risk Phrases R11;R20/22;R29;R50
Safety Phrases S61
RIDADR UN 1340 4.3/PG 2
WGK Germany 3
RTECS TH4375000
Packaging Group II
Hazard Class 4.3
HS Code 2813900010

 Customs

HS Code 2813900010

 Articles3

More Articles
New synthetic routes to poly (isothianaphthene) I. Reaction of phthalic anhydride and phthalide with phosphorus pentasulfide. van Asselt R, et al.

Synthetic Metals 74(1) , 65-70, (1995)

Thiation with phosphorus pentasulfide in pyridine solution. Klingsberg E and Papa D.

J. Am. Chem. Soc. 73(10) , 4988-4989, (1951)

Phosphorus (V) sulfide. Edmondson SD and Sannigrahi M.

e-EROS Encyclopedia of Reagents for Organic Synthesis. , (2004)

 Synonyms

Phosphoric Sulphide
sulfurphosphide
Phosphorus(V) sulfide
Phosphorussulfid
EINECS 215-242-4
sirnikfosforecny
MFCD00011441
osphorus pentasulf
PHOSPHORUS SULFIDE
Phosphoruspersulfide
Phosphoricsulfide
rcrawastenumberu189
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