1,3-dithian-2-yl(trimethyl)silane

Modify Date: 2024-01-02 06:43:51

1,3-dithian-2-yl(trimethyl)silane Structure
1,3-dithian-2-yl(trimethyl)silane structure
Common Name 1,3-dithian-2-yl(trimethyl)silane
CAS Number 13411-42-2 Molecular Weight 192.417
Density 1.0±0.1 g/cm3 Boiling Point 261.7±0.0 °C at 760 mmHg
Molecular Formula C7H16S2Si Melting Point N/A
MSDS Chinese USA Flash Point 96.1±0.0 °C

 Names

Name 2-trimethylsilyl-1,3-dithiane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 261.7±0.0 °C at 760 mmHg
Molecular Formula C7H16S2Si
Molecular Weight 192.417
Flash Point 96.1±0.0 °C
Exact Mass 192.046265
PSA 50.60000
LogP 2.65
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.513

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)
Safety Phrases S23-S24/25
RIDADR 3334
WGK Germany 3
HS Code 2934999090

 Synthetic Route

~87%

1,3-dithian-2-yl(trimethyl)silane Structure

1,3-dithian-2-y...

CAS#:13411-42-2

Literature: Porskamp, P. A. T. W.; Leij, M. van der; Lammerink, B. H. M.; Zwanenburg, B. Recueil: Journal of the Royal Netherlands Chemical Society, 1983 , vol. 102, # 9 p. 400 - 404

~85%

1,3-dithian-2-yl(trimethyl)silane Structure

1,3-dithian-2-y...

CAS#:13411-42-2

Literature: Page, Philip C. Bulman; van Niel, Monique B.; Westwood, Donald Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 269 - 276

~%

1,3-dithian-2-yl(trimethyl)silane Structure

1,3-dithian-2-y...

CAS#:13411-42-2

Literature: Liebigs Annalen der Chemie, , # 5 p. 944 - 949

 Customs

HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles4

More Articles
Multicomponent linchpin couplings. Reaction of dithiane anions with terminal epoxides, epichlorohydrin, and vinyl epoxides: efficient, rapid, and stereocontrolled assembly of advanced fragments for complex molecule synthesis.

J. Am. Chem. Soc. 125 , 14435, (2003)

The development, application, and advantages of a one-flask multicomponent dithiane linchpin coupling protocol, over the more conventional stepwise addition of dithiane anions to electrophiles leading...

Lewis base catalyzed 1,3-dithiane addition to carbonyl and imino compounds using 2-trimethylsilyl-1,3-dithiane.

Chem. Asian J. 3(8-9) , 1592-600, (2008)

Lewis base-catalyzed 1,3-dithiane addition to electrophiles such as carbonyl compounds and N-substituted aldimines with 2-trimethylsilyl-1,3-dithiane (TMS-dithiane) is described. By the activation of ...

Smith, A. B., III; Boldi, A. M.

J. Am. Chem. Soc. 119 , 6925, (1997)

 Synonyms

1,3-Dithian-2-yltrimethylsilane
(1,3-Dithian-2-yl)trimethylsilane
2-Trimethylsilyl-1,3-dithiane
1,3-dithian-2-yl(trimethyl)silane
Silane, 1,3-dithian-2-yltrimethyl-
EINECS 236-504-4
MFCD00006655