(R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine structure
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Common Name | (R,R)-(-)-N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine | ||
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CAS Number | 135616-40-9 | Molecular Weight | 546.826 | |
Density | 1.0±0.1 g/cm3 | Boiling Point | 615.2±55.0 °C at 760 mmHg | |
Molecular Formula | C36H54N2O2 | Melting Point | 205-207ºC | |
MSDS | Chinese USA | Flash Point | 421.6±20.8 °C | |
Symbol |
GHS07 |
Signal Word | Warning |
Name | (R,R)-(-)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine |
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Synonym | More Synonyms |
Density | 1.0±0.1 g/cm3 |
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Boiling Point | 615.2±55.0 °C at 760 mmHg |
Melting Point | 205-207ºC |
Molecular Formula | C36H54N2O2 |
Molecular Weight | 546.826 |
Flash Point | 421.6±20.8 °C |
Exact Mass | 546.418518 |
PSA | 65.18000 |
LogP | 11.18 |
Vapour Pressure | 0.0±1.8 mmHg at 25°C |
Index of Refraction | 1.536 |
Symbol |
GHS07 |
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Signal Word | Warning |
Hazard Statements | H315-H319-H335 |
Precautionary Statements | P261-P305 + P351 + P338 |
Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
Hazard Codes | Xi |
Risk Phrases | R36/37/38 |
Safety Phrases | S26-S36 |
RIDADR | NONH for all modes of transport |
WGK Germany | 3 |
~99% (R,R)-(-)-N,N'-... CAS#:135616-40-9 |
Literature: Nakano, Tamaki; Yade, Tohru; Okamoto, Yoshio Macromolecules, 2003 , vol. 36, # 10 p. 3498 - 3504 |
~% (R,R)-(-)-N,N'-... CAS#:135616-40-9 |
Literature: Journal of Organic Chemistry, , vol. 71, # 7 p. 2903 - 2906 |
~% (R,R)-(-)-N,N'-... CAS#:135616-40-9 |
Literature: Tetrahedron Letters, , vol. 46, # 22 p. 3829 - 3830 |
~% (R,R)-(-)-N,N'-... CAS#:135616-40-9 |
Literature: Journal of Organic Chemistry, , vol. 59, # 7 p. 1939 - 1942 |
~89% (R,R)-(-)-N,N'-... CAS#:135616-40-9 |
Literature: President and Fellows of Harvard College Patent: US6369223 B2, 2002 ; Location in patent: Page column 56 ; |
E.N. Jacobsen et al.
J. Am. Chem. Soc. 113 , 7063, (1991)
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L. Deng, E.N. Jacobsen
J. Org. Chem. 57 , 4320, (1992)
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J. Am. Chem. Soc. 113 , 7063, (1991)
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MFCD00191800 |
(R,R)-(-)-N,N‘-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine |
Phenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis[nitrilo(E)methylidyne]]bis[4,6-bis(1,1-dimethylethyl)- |
2,2'-{(1R,2R)-Cyclohexane-1,2-diylbis[nitrilo(E)methylylidene]}bis(4,6-di-tert-butylphenol) |
(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE |
(R,R)-Jacobsen's Ligand |
(R,R)-(-)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine |
(1R,2R)-N,N′-bis-[3,5-di-tert-butyl-salicylidene]-1,2-cyclohexanediamine |
2,2'-{(1R,2R)-1,2-Cyclohexanediylbis[nitrilo(E)methylylidene]}bis[4,6-bis(2-methyl-2-propanyl)phenol] |