N-(2-Hydroxyethyl)-2-Methylaniline

Modify Date: 2024-01-10 14:07:29

N-(2-Hydroxyethyl)-2-Methylaniline Structure
N-(2-Hydroxyethyl)-2-Methylaniline structure
 Common Name N-(2-Hydroxyethyl)-2-Methylaniline
CAS Number 136-80-1 Molecular Weight 151.20600
Density 1.086g/cm3 Boiling Point 285.5ºC at 760 mmHg
Molecular Formula C9H13NO Melting Point N/A
MSDS N/A Flash Point 145.6ºC

 Names

Name 2-(2-methylanilino)ethanol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.086g/cm3
Boiling Point 285.5ºC at 760 mmHg
Molecular Formula C9H13NO
Molecular Weight 151.20600
Flash Point 145.6ºC
Exact Mass 151.10000
PSA 32.26000
LogP 1.47220
Vapour Pressure 0.00131mmHg at 25°C
Index of Refraction 1.588
Storage condition 2-8°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
KM3325000
CHEMICAL NAME :
Ethanol, 2-toluidino-
CAS REGISTRY NUMBER :
136-80-1
BEILSTEIN REFERENCE NO. :
1210606
LAST UPDATED :
199701
DATA ITEMS CITED :
5
MOLECULAR FORMULA :
C9-H13-N-O
MOLECULAR WEIGHT :
151.23
WISWESSER LINE NOTATION :
Q2MR B1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,693,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,693,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 31,60,1949

 Safety Information

Hazard Codes Xi: Irritant;
HS Code 2921499090

 Synthetic Route

2-Bromotoluene structure

2-Bromotoluene

CAS#:95-46-5
2-Aminoethanol structure

2-Aminoethanol

CAS#:141-43-5

~95%

N-(2-Hydroxyethyl)-2-Methylaniline Structure

N-(2-Hydroxyeth...

CAS#:136-80-1
Literature: Yin, Huiqing; Jin, Ming; Chen, Wei; Chen, Chen; Zheng, Likang; Wei, Ping; Han, Shiqing Tetrahedron Letters, 2012 , vol. 53, # 10 p. 1265 - 1270
2-Indoethanol structure

2-Indoethanol

CAS#:624-76-0
o-Toluidine structure

o-Toluidine

CAS#:95-53-4

~85%

N-(2-Hydroxyethyl)-2-Methylaniline Structure

N-(2-Hydroxyeth...

CAS#:136-80-1
Literature: Bhanu Prasad; Gilbertson, Scott R. Organic Letters, 2009 , vol. 11, # 16 p. 3710 - 3713
2-chloroethyl N-(2-methylphenyl)carbamate structure

2-chloroethyl N...

CAS#:90869-76-4

~%

N-(2-Hydroxyethyl)-2-Methylaniline Structure

N-(2-Hydroxyeth...

CAS#:136-80-1
Literature: Journal of the American Chemical Society, , vol. 45, p. 789
o-Toluidine structure

o-Toluidine

CAS#:95-53-4

~%

N-(2-Hydroxyethyl)-2-Methylaniline Structure

N-(2-Hydroxyeth...

CAS#:136-80-1
Literature: Journal of the American Chemical Society, , vol. 45, p. 789
2-(chloroamino)ethanol structure

2-(chloroamino)...

CAS#:52316-60-6
Toluene structure

Toluene

CAS#:108-88-3

~3%

N-(2-hydroxyethyl)-m-toluidine structure

N-(2-hydroxyeth...

CAS#:102-41-0
2-[(4-methylphenyl)amino]ethanol structure

2-[(4-methylphe...

CAS#:2933-74-6
Detail
Literature: Doklady Chemistry, , vol. 308, # 4-6 p. 295 - 298 Dokl. Akad. Nauk SSSR Ser. Khim., , vol. 308, # 5 p. 1150 - 1154
o-Toluidine structure

o-Toluidine

CAS#:95-53-4
2-Chloroethanol structure

2-Chloroethanol

CAS#:107-07-3

~68%

N-(2-Hydroxyethyl)-2-Methylaniline Structure

N-(2-Hydroxyeth...

CAS#:136-80-1
Literature: Aksac, Z.; Altinok, A.; Icli, S. Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1983 , vol. 39, # 12 p. 1029 - 1032
ETHYLENE OXIDE structure

ETHYLENE OXIDE

CAS#:75-21-8
o-Toluidine structure

o-Toluidine

CAS#:95-53-4

~%

N-(2-Hydroxyethyl)-2-Methylaniline Structure

N-(2-Hydroxyeth...

CAS#:136-80-1
Literature: Trudy Inst.Chim.Charkovsk.Univ.Chem.Abstr., , vol. 3, p. 45,50 Trudy Inst.Chim.Charkovsk.Univ.Chem.Abstr., , p. 1024

 Customs

HS Code 2921499090
Summary 2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

Emery 5711
2-o-Toluidino-aethanol
o-Toluidino ethanol
ETHANOL,2-TOLUIDINO
o-Tolyl ethanolamine
N-(2-Hydroxyethyl)-o-toluidine
N-(2-Hydroxyethyl)-2-Methylaniline
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