nickel(ii) fluoride tetrahydrate

Synonym:Nickel difluoride hydrate, Nickelous fluoride hydrate

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Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound13940-83-560%0.1mg/m3 (as Ni)1mg/m3 (as Ni)

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Section 3: Hazards Identification
Irritating to skin, eyes and respiratory tract. May cause sensitization by inhalation and skin contact. May cause
Emergency Overview:
fluoride poisoning. May cause cancer.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes.
Eye Contact:Causes irritation and serious eye damage. Effects may not immediately appear.
Causes irritation, with delayed redness and pain. Soluble fluoride may be corrosive. Nickel salts may lead to
Skin Contact:
dermatitis.
Inhalation:May cause sensitization by inhalation. Inhalation causes severe irritation to the respiratory tract.
Ingestion:May cause salivation, nausea, vomiting, diarrhea, and abdominal pain.
Fluoride poisoning may cause nausea, vomiting, diarrhea, weakness, coma, and cardiovascular collapse.
Acute Health Affects:
Nickel salts may cause convulsions, asphyxia, and sensitization dermatitis.
Prolonged exposure to hydrolysable fluorine compounds can cause deterioration of bone and tooth structure.
Chronic Health Affects:Prolonged exposure to nickel and nickel compounds may lead to skin irritation and dermatitis. May cause
cancer.
NTP:Yes
IARC:Yes
OSHA:No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Apply calcium gluconate jelly
Skin Exposure:
or water soluble calcium salts as antidote. Seek medical assistance.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:None. Material is non-flammable.
Special Fire Fighting Procedures:No special fire fighting procedures required.
Hazardous Combustion andIf involved in a fire this material may emit corrosive fumes of hydrofluoric acid.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.

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SECTION 7: Handling and Storage
Handling and Storage:Store solid in a tightly sealed container.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
Respirator:
requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:green pwdr.
Molecular Weight:96.71 (168.77)
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:

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SECTION 10: Stability and Reactivity
Stability:air and moisture stable
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:none
Incompatibility:none
Decomposition Products:Metal fluorides and water

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SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:Carcinogen (as Ni)
Mutagenic Effects:no data
Tetratogenic Effects:no data

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SECTION 12: Ecological Information
Ecological Information:No information available

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SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

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SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound: See Category Code N495 for reporting.
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A