1-deoxy-1-nitro-d-mannitol

Modify Date: 2024-01-09 17:43:02

1-deoxy-1-nitro-d-mannitol Structure
1-deoxy-1-nitro-d-mannitol structure
Common Name 1-deoxy-1-nitro-d-mannitol
CAS Number 14199-83-8 Molecular Weight 211.17000
Density 1.632g/cm3 Boiling Point 608.3ºC at 760mmHg
Molecular Formula C6H13NO7 Melting Point 133ºC
MSDS N/A Flash Point 268.9ºC

 Names

Name 6-nitrohexane-1,2,3,4,5-pentol
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.632g/cm3
Boiling Point 608.3ºC at 760mmHg
Melting Point 133ºC
Molecular Formula C6H13NO7
Molecular Weight 211.17000
Flash Point 268.9ºC
Exact Mass 211.06900
PSA 146.97000
Appearance of Characters Crystalline Powder | White to almost white
Vapour Pressure 2.45E-17mmHg at 25°C
Index of Refraction 1.585

 MSDS

Name: 1-Deoxy-1-Nitro-D-Mannitol 99% Material Safety Data Sheet
Synonym: None Known
CAS: 14199-83-8
Section 1 - Chemical Product MSDS Name:1-Deoxy-1-Nitro-D-Mannitol 99% Material Safety Data Sheet
Synonym:None Known

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
14199-83-8 1-Deoxy-1-Nitro-D-Mannitol 99% 238-051-8
Hazard Symbols: None Listed.
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May be harmful if inhaled.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with eyes, skin, and clothing.
Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 14199-83-8: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 133 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H13NO7
Molecular Weight: 211.17

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 14199-83-8 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-Deoxy-1-Nitro-D-Mannitol - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 14199-83-8: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 14199-83-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 14199-83-8 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Safety Phrases 24/25
WGK Germany 3
HS Code 2905590090

 Synthetic Route

~24%

1-deoxy-1-nitro-d-mannitol Structure

1-deoxy-1-nitro...

CAS#:14199-83-8

Literature: Liebigs Annalen der Chemie, , # 3 p. 201 - 206

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1-deoxy-1-nitro-d-mannitol Structure

1-deoxy-1-nitro...

CAS#:14199-83-8

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. <4> 8, p. 33,35 Journal of the American Chemical Society, , vol. 80, p. 2236

~%

1-deoxy-1-nitro-d-mannitol Structure

1-deoxy-1-nitro...

CAS#:14199-83-8

Detail
Literature: Journal of the American Chemical Society, , vol. 69, p. 1965

 Customs

HS Code 2905590090
Summary 2905590090 other halogenated, sulphonated, nitrated or nitrosated derivatives of acyclic alcohols。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

 Synonyms

6-Nitro-D-rhamnit
MFCD00024829
1-nitro-D-1-deoxy-mannitol
1-Desoxy-1-nitro-D-mannitol
1-Nitro-1-deoxy-D-mannitol
EINECS 238-051-8
1-DEOXY-1-NITRO-D-MANNITOL
1-deoxy-1-nitro-D-manno-hexitol
1-Nitro-1-desoxy-D-mannit
6-Nitro-D-manno-hexan-1,2,3,4,5-pentaol
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