Molybdenum(II) acetate dimer structure
|
Common Name | Molybdenum(II) acetate dimer | ||
---|---|---|---|---|
CAS Number | 14221-06-8 | Molecular Weight | 428.09600 | |
Density | N/A | Boiling Point | 117.1ºC at 760 mmHg | |
Molecular Formula | C8H12Mo2O8 | Melting Point | N/A | |
MSDS | Chinese USA | Flash Point | N/A |
Name | molybdenum(2+),tetraacetate |
---|---|
Synonym | More Synonyms |
Boiling Point | 117.1ºC at 760 mmHg |
---|---|
Molecular Formula | C8H12Mo2O8 |
Molecular Weight | 428.09600 |
Exact Mass | 431.86400 |
PSA | 105.20000 |
LogP | 0.05520 |
Vapour Pressure | 13.9mmHg at 25°C |
Storage condition | ?20°C |
Water Solubility | Slightly soluble in organic solvents. Insoluble in water. |
Section 1: Product Identification Chemical Name:Molybdenum (II) acetate dimer,99% CAS Registry Number:14221-06-8 Formula:Mo2(OOCCH3)4 EINECS Number:238-089-5 Chemical Family:metal acetate salt Synonym:Molybdenum diacetate
Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound14221-06-8100%10mg/m3 (as Mo -15mg/m3 Section 3: Hazards Identification Emergency Overview:Irritating to eyes and skin. May be harmful if swallowed or inhaled. Primary Routes of Exposure:Ingestion Eye Contact:Causes mild irritation of the eyes. Skin Contact:Causes slight irritation of the skin. Inhalation:Inhalation of dust may lead to irritation of the respiratory tract. Ingestion:No information is available on the physiological effects of ingestion. May be harmful if swallowed. Acute Health Affects:Irritating to eyes and skin. May be harmful if swallowed or inhaled. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, dry powder or foam If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained Special Fire Fighting Procedures: breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes. Decomposion Products: Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage: SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:Material may form a fine dust. If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:yellow xtl. Molecular Weight:428.06 Melting Point:no data Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:insoluble SECTION 10: Stability and Reactivity Stability:air sensitive, (store cold) Hazardous Polymerization:no hazardous polymerization Conditions to Avoid:prolonged exposure to air Incompatibility:oxidizing agents Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, and molybdenum salts. SECTION 11: Toxicological Information RTECS Data:No information available in the RTECS files. Carcinogenic Effects:No data available Mutagenic Effects:No data available Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No information available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Non-hazardous Hazard Class (CFR):NA Additional Hazard Class (CFR):NA Packaging Group (CFR):NA UN ID Number (CFR):NA Shipping Name (IATA):Non-hazardous Hazard Class (IATA):NA Additional Hazard Class (IATA):NA Packaging Group (IATA):NA UN ID Number (IATA):NA SECTION 15: Regulatory Information TSCA:Not listed in the TSCA inventory. SARA (Title 313):Not reportable under SARA Title 313. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A |
~90% Molybdenum(II) ... CAS#:14221-06-8 |
Literature: Johnson, Kara D.; Powell, Gregory L. Journal of Organometallic Chemistry, 2008 , vol. 693, # 8-9 p. 1712 - 1715 |
~0% Molybdenum(II) ... CAS#:14221-06-8 |
Literature: Birnbaum, Amira; Cotton, F. Albert; Dori, Zvi; Kapon, Moshe; Marler, David; Reisner, George M. Journal of the American Chemical Society, 1985 , vol. 107, # 8 p. 2405 - 2410 |
~66% Molybdenum(II) ... CAS#:14221-06-8 |
Literature: Baghurst, David R.; Mingos, D. Michael P. Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1992 , # 7 p. 1151 - 1156 |
~58% Molybdenum(II) ... CAS#:14221-06-8 |
Literature: Menezes, Jose C.; Romao, Carlos C. Polyhedron, 1990 , vol. 9, p. 1237 - 1240 |
~69% Molybdenum(II) ... CAS#:14221-06-8 |
Literature: Wu, Ying-Yann; Chen, Jhy-Der; Liou, Lin-Shu; Wang, Ju-Chun Inorganica Chimica Acta, 1997 , vol. 258, p. 193 - 200 |
~63% Molybdenum(II) ... CAS#:14221-06-8 |
Literature: Wu, Ying-Yann; Chen, Jhy-Der; Liou, Lin-Shu; Wang, Ju-Chun Inorganica Chimica Acta, 1997 , vol. 258, p. 193 - 200 |
~71% Molybdenum(II) ... CAS#:14221-06-8 |
Literature: Jawiczuk, Magdalena; Gorecki, Marcin; Suszczynska, Agata; Karchier, Michal; Jazwinski, Jaroslaw; Frelek, Jadwiga Inorganic Chemistry, 2013 , vol. 52, # 14 p. 8250 - 8263 |
HS Code | 2915900090 |
---|---|
Summary | 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0% |
MFCD00013395 |
tetra (aceto) dimolybdenum |
Mo2(CH3COO)4 |
EINECS 238-089-5 |
Di-molybdenum tetraacetate |
Molybdenum(II) acetate |
Dimolybdenum tetraacetate |
Molybdenum(II) acetate dimer |
molybdenum(2+) tetraacetate |
molybdenum(2+) acetate(1:2) |
Mo2(acetate)4 |