bis(3-bicyclo[2.2.1]heptanyl)phosphane

Synonym:none

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Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound148432-44-4100%no datano data

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Section 3: Hazards Identification
Harmful by inhalation, in contact with skin and if swallowed. Material has a pungent odor. Inhalation of vapors
Emergency Overview:
may lead to headache and dizziness.
Primary Routes of Exposure:Ingestion, inhalation, skin
Eye Contact:May cause mild to severe irritation of the eyes.
Skin Contact:Liquid may burst in to flame in air, causing thermal burns to skin. Harmful in contact with skin.
The material has a pungent odor. Harmful by inhalation. Inhalation may lead to headaches, dizziness and
Inhalation:
irritation of the respiratory tract.
Ingestion:Harmful if swallowed. May cause vomiting and diarrhea.
Harmful by inhalation, in contact with skin and if swallowed. May be irritating to skin, eyes and respiratory
Acute Health Affects:
tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:Pyrophoric
Explosion Limits:Pyrophoric
Extinguishing Medium:carbon dioxide, dry powder or foam.
The pyrophoric liquid may reignite. Fire fighters should be equipped with an approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic organic fumes and vapors of phosphorus pentoxide.
Decomposion Products:
Unusual Fire or Explosion Hazards: Material is pyrophoric. May spontaneously ignite if exposed to air.

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SECTION 6: Accidental Release Measures
Material may spontaneously ignite. Spillage in areas not adequately ventilated will require evacuation of site.
Spill and Leak Procedures:Emergency response teams will require self-contained breathing apparatus. Small spills can be mixed with
vermiculite or other suitable absorbents and placed in a sealed metal can.

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SECTION 7: Handling and Storage
Handling and Storage:Material must be handled and stored under an inert atmosphere of nitrogen or argon.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Material has a pungent odor. Always handle in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Material has a pungent odor. Always handle in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:colorless liquid
Molecular Weight:222.31
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:pungent odor
Solubility in Water:insoluble

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SECTION 10: Stability and Reactivity
Stability:air-sensitive, pyrophoric
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:Keep away from moisture, air, heat and ignition sources including open flame and electrostatic discharge.
Incompatibility:oxidizing agents and halogens
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes and phosphorus oxides.

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SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

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SECTION 12: Ecological Information
Ecological Information:No information available

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SECTION 13: Disposal Considerations
Disposal:Dispose of according to federal, state, and local regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Pyrophoric liquids, organic, N.O.S.
Hazard Class (CFR):4.2
Additional Hazard Class (CFR):NA
Packaging Group (CFR):I
UN ID Number (CFR):UN# 2845
Shipping Name (IATA):Forbidden
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

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SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A