Methyl 4-bromo-3-methylbenzoate

Modify Date: 2024-01-03 18:38:03

Methyl 4-bromo-3-methylbenzoate Structure
Methyl 4-bromo-3-methylbenzoate structure
Common Name Methyl 4-bromo-3-methylbenzoate
CAS Number 148547-19-7 Molecular Weight 229.071
Density 1.4±0.1 g/cm3 Boiling Point 287.4±20.0 °C at 760 mmHg
Molecular Formula C9H9BrO2 Melting Point 38-44 °C(lit.)
MSDS Chinese USA Flash Point 127.6±21.8 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name Methyl 4-bromo-3-methylbenzoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 287.4±20.0 °C at 760 mmHg
Melting Point 38-44 °C(lit.)
Molecular Formula C9H9BrO2
Molecular Weight 229.071
Flash Point 127.6±21.8 °C
Exact Mass 227.978592
PSA 26.30000
LogP 3.41
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.545

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S36
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2916399090

 Synthetic Route

~99%

Methyl 4-bromo-3-methylbenzoate Structure

Methyl 4-bromo-...

CAS#:148547-19-7

Literature: Alam, Muzaffar; Du Bois, Daisy Joe; Hawley, Ronald Charles; Kennedy-Smith, Joshua; Minatti, Ana Elena; Palmer, Wylie Solang; Silva, Tania; Wilhelm, Robert Stephen Patent: US2011/71150 A1, 2011 ; Location in patent: Page/Page column 33 ;

~%

Methyl 4-bromo-3-methylbenzoate Structure

Methyl 4-bromo-...

CAS#:148547-19-7

Literature: US2003/8863 A1, ;

~81%

Methyl 4-bromo-3-methylbenzoate Structure

Methyl 4-bromo-...

CAS#:148547-19-7

Literature: WAKAMOTO PHARMACEUTICAL CO., LTD. Patent: WO2006/51851 A1, 2006 ; Location in patent: Page/Page column 65 ;

~%

Methyl 4-bromo-3-methylbenzoate Structure

Methyl 4-bromo-...

CAS#:148547-19-7

Literature: Bioorganic and Medicinal Chemistry Letters, , vol. 19, # 15 p. 4416 - 4420

 Customs

HS Code 2916399090
Summary 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Articles1

More Articles
Synthesis and properties of mesogen-jacketed liquid crystalline polymers with asymmetry mesogenic core. Chen S, et al.

Macromolecules 40(16) , 5718-5725, (2007)

 Synonyms

Methyl-4-brom-3-methylbenzolcarboxylat
3-Bromo-p-toluic Acid Methyl Ester
4-Bromo-3-methylbenzoic Acid Methyl Ester
Methyl 3-Bromo-p-toluate
3-bromo-4-methyl-benzoic acid methyl ester
Methyl 4-bromo-3-methylbenzoate
Methyl 3-Bromo-4-Methylbenzoate
methyl 3-bromotoluate
METHYL4-BROMO-3-METHYLBENZOATE
4-Bromo-3-methyl-benzoic acid methyl ester
Methyl 4-Bromo-m-toluate
Methyl3-bromo-4-methylbenzoate
Benzoic acid, 4-bromo-3-methyl-, methyl ester
4-Bromo-m-toluic Acid Methyl Ester
methyl 3-methyl-4-bromobenzoate
MFCD00673014
3-Bromo-4-methylbenzoic Acid Methyl Ester