1,1'-Biphenyl,4-(trimethylsilyl)-

Modify Date: 2024-01-09 11:45:36

1,1'-Biphenyl,4-(trimethylsilyl)- Structure
1,1'-Biphenyl,4-(trimethylsilyl)- structure
 Common Name 1,1'-Biphenyl,4-(trimethylsilyl)-
CAS Number 1625-88-3 Molecular Weight 226.38900
Density 0.96g/cm3 Boiling Point 307.6ºC at 760mmHg
Molecular Formula C15H18Si Melting Point N/A
MSDS N/A Flash Point 125.7ºC

 Names

Name trimethyl-(4-phenylphenyl)silane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.96g/cm3
Boiling Point 307.6ºC at 760mmHg
Molecular Formula C15H18Si
Molecular Weight 226.38900
Flash Point 125.7ºC
Exact Mass 226.11800
LogP 3.89880
Vapour Pressure 0.0013mmHg at 25°C
Index of Refraction 1.543

 Safety Information

Hazard Codes Xi

 Synthetic Route

Hexamethyldisilane structure

Hexamethyldisilane

CAS#:1450-14-2

4-Bromobiphenyl structure

4-Bromobiphenyl

CAS#:92-66-0

~79%

1,1'-Biphenyl,4-(trimethylsilyl)- Structure

1,1'-Biphenyl,4...

CAS#:1625-88-3

Literature: Shirakawa; Kurahashi; Yoshida; Hiyama Chemical Communications, 2000 , # 19 p. 1895 - 1896
Chlorotrimethylsilane structure

Chlorotrimethyl...

CAS#:75-77-4

4-Chlorobiphenyl structure

4-Chlorobiphenyl

CAS#:2051-62-9

~81%

1,1'-Biphenyl,4-(trimethylsilyl)- Structure

1,1'-Biphenyl,4...

CAS#:1625-88-3

Literature: Clark, H. A.; Gordon, A. F.; Young, C. W.; Hunter, M. J. Journal of the American Chemical Society, 1951 , vol. 73, p. 3798 - 3803 Full Text View citing articles Show Details Gmelin Handbook: Si: MVol.C, 28, page 86 - 90
Bromobenzene structure

Bromobenzene

CAS#:108-86-1

N/A structure

N/A

CAS#:107134-80-5

~74%

1,1'-Biphenyl,4-(trimethylsilyl)- Structure

1,1'-Biphenyl,4...

CAS#:1625-88-3

Literature: Kaufmann, Dieter Chemische Berichte, 1987 , vol. 120, p. 901 - 906
Chlorotrimethylsilane structure

Chlorotrimethyl...

CAS#:75-77-4

1-phenyl-4-(trifluoromethoxy)benzene structure

1-phenyl-4-(tri...

CAS#:71274-84-5

~30%

Biphenyl structure

Biphenyl

CAS#:92-52-4

1,1'-Biphenyl,4-(trimethylsilyl)- Structure

1,1'-Biphenyl,4...

CAS#:1625-88-3

Literature: Iijima, Akinori; Amii, Hideki Tetrahedron Letters, 2008 , vol. 49, # 41 p. 6013 - 6015
(4-Chlorophenyl)(trimethyl)silane structure

(4-Chlorophenyl...

CAS#:10557-71-8

benzene structure

benzene

CAS#:71-43-2

~49%

1,1'-Biphenyl,4-(trimethylsilyl)- Structure

1,1'-Biphenyl,4...

CAS#:1625-88-3

Literature: Qrareya, Hisham; Raviola, Carlotta; Protti, Stefano; Fagnoni, Maurizio; Albini, Angelo Journal of Organic Chemistry, 2013 , vol. 78, # 12 p. 6016 - 6024
n-Butyllithium structure

n-Butyllithium

CAS#:109-72-8

4-Bromobiphenyl structure

4-Bromobiphenyl

CAS#:92-66-0

~%

1,1'-Biphenyl,4-(trimethylsilyl)- Structure

1,1'-Biphenyl,4...

CAS#:1625-88-3

Literature: Benkeser et al. Journal of the American Chemical Society, 1958 , vol. 80, p. 2279,2282
Chlorotrimethylsilane structure

Chlorotrimethyl...

CAS#:75-77-4

4-Bromobiphenyl structure

4-Bromobiphenyl

CAS#:92-66-0

~%

1,1'-Biphenyl,4-(trimethylsilyl)- Structure

1,1'-Biphenyl,4...

CAS#:1625-88-3

Literature: Marcinow, Z.; Clawson, D. K.; Rabideau, P. W. Tetrahedron, 1989 , vol. 45, # 17 p. 5441 - 5448

 Synonyms

4'-trimethylsilylbiphenyl
Biphenyl-4-yl-trimethyl-silan
biphenyl-4-yltrimethylsilane
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