Trost ligand

Modify Date: 2024-01-06 22:15:32

Trost ligand structure	Common Name	Trost ligand
	CAS Number	172138-95-3	Molecular Weight	324.377
	Density	1.3±0.1 g/cm3	Boiling Point	663.4±50.0 °C at 760 mmHg
	Molecular Formula	C₁₈H₂₀N₄O₂	Melting Point	170ºC
	MSDS	Chinese USA	Flash Point	355.0±30.1 °C
	Symbol	GHS07	Signal Word	Warning

Name	N-[(1S,2S)-2-(pyridine-2-carbonylamino)cyclohexyl]pyridine-2-carboxamide
Synonym	More Synonyms

Density	1.3±0.1 g/cm3
Boiling Point	663.4±50.0 °C at 760 mmHg
Melting Point	170ºC
Molecular Formula	C₁₈H₂₀N₄O₂
Molecular Weight	324.377
Flash Point	355.0±30.1 °C
Exact Mass	324.158630
PSA	83.98000
LogP	0.77
Vapour Pressure	0.0±2.0 mmHg at 25°C
Index of Refraction	1.610

Trost ligand MSDS(Chinese)

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H302-H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes	Xn: Harmful;
Risk Phrases	R36/37/38
Safety Phrases	26-36/37/39
RIDADR	NONH for all modes of transport

2-Picolinic acid structure

2-Picolinic acid

CAS#:98-98-6

(1S,2S)-(+)-1,2-Diaminocyclohexane structure

(1S,2S)-(+)-1,2...

CAS#:21436-03-3

~84%

Trost ligand Structure

Trost ligand

CAS#:172138-95-3

Literature: Conlon, David A.; Yasuda, Nobuyoshi Advanced Synthesis and Catalysis, 2001 , vol. 343, # 1 p. 137 - 138

Ethyl 2-picolinate structure

Ethyl 2-picolinate

CAS#:2524-52-9

(1S,2S)-(+)-1,2-Diaminocyclohexane structure

(1S,2S)-(+)-1,2...

CAS#:21436-03-3

~79%

Trost ligand Structure

Trost ligand

CAS#:172138-95-3

Literature: Morimoto, Hiroyuki; Fujiwara, Risa; Shimizu, Yuhei; Morisaki, Kazuhiro; Ohshima, Takashi Organic Letters, 2014 , vol. 16, # 7 p. 2018 - 2021

carbon monoxide structure

carbon monoxide

CAS#:201230-82-2

Pyridyl p-tolylsulfonate structure

Pyridyl p-tolyl...

CAS#:57785-86-1

(1S,2S)-(+)-1,2-Diaminocyclohexane structure

(1S,2S)-(+)-1,2...

CAS#:21436-03-3

~74%

Trost ligand Structure

Trost ligand

CAS#:172138-95-3

Literature: Hermange, Philippe; Lindhardt, Anders T.; Taaning, Rolf H.; Bjerglund, Klaus; Lupp, Daniel; Skrydstrup, Troels Journal of the American Chemical Society, 2011 , vol. 133, # 15 p. 6061 - 6071

Precursor 4
CAS#:98-98-6 2-Picolinic acid CAS#:21436-03-3 (1S,2S)-(+)-1,2... CAS#:2524-52-9 Ethyl 2-picolinate CAS#:201230-82-2 carbon monoxide
DownStream 0

Asymmetric Transition Metal-Catalyzed Allylic Alkylations.

Chem. Rev. 96 , 395, (1996)

Asymmetric transition-metal-catalyzed allylic alkylations: applications in total synthesis.

Chem. Rev. 103 , 2921, (2003)

Trost, B.M. et al.

J. Am. Chem. Soc. 124 , 11616, (2004)

(1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane

Trost ligand

N,N'-(1S,2S)-1,2-Cyclohexanediyldi(2-pyridinecarboxamide)

2-Pyridinecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis-

(1S,2S)-N,N′-1,2-Cyclohexanediylbis(2-pyridinecarboxamide)

(S,S)-DACH-pyridyl Trost ligand

MFCD02684543

Shanghai Nianxing Industrial Co., Ltd
China
Product Name: Trost ligand
Price: Negotiable
Purity: 98.0%
Delivery: 10 Day
Contact: Huang
Email: sales@echemcloud.com

Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: N,N'-((1S,2S)-CYCLOHEXANE-1,2-DIYL)DIPICOLINAMIDE
Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
Purity: 98.0%
Delivery: Inquiry
Contact: Ms Wang
Email: enquiry@dycnchem.com

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