Carbonylhydridotris(triphenylphosphine)iridium(I)

Modify Date: 2024-01-14 07:56:56

Carbonylhydridotris(triphenylphosphine)iridium(I) Structure
Carbonylhydridotris(triphenylphosphine)iridium(I) structure
Common Name Carbonylhydridotris(triphenylphosphine)iridium(I)
CAS Number 17250-25-8 Molecular Weight 1007.08000
Density N/A Boiling Point 360ºC at 760mmHg
Molecular Formula C55H45IrOP3 Melting Point 170ºC (dec.)
MSDS N/A Flash Point 181.7ºC

 Names

Name Carbonylhydridotris(triphenylphosphine)iridium(I)
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 360ºC at 760mmHg
Melting Point 170ºC (dec.)
Molecular Formula C55H45IrOP3
Molecular Weight 1007.08000
Flash Point 181.7ºC
Exact Mass 1007.23000
PSA 40.77000
LogP 10.12640
Vapour Pressure 4.74E-05mmHg at 25°C

 MSDS


Section 1: Product Identification
Chemical Name:Hydridocarbonyltris(triphenylphosphine)iridium (I), 99%
CAS Registry Number:17250-25-8
Formula:IrH(CO)[(C6H5)3P]3
EINECS Number:none
Chemical Family:metal carbonyl complexes
Synonym:none

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound17250-25-8100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes
Eye Contact:Causes slight or mild irritation of the eyes.
Skin Contact:Causes slight to mild irritation of the skin.
Inhalation:Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information on the physiological effects of ingestion.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Handling and Storage:Store in a tightly sealed container. Keep away from heat and direct sunlight.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
If ventilation is not available, a respirator should be worn. The use of respirators requires a Respiratory
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:light yellow pwdr.
Molecular Weight:1008.12
Melting Point:170° dec.
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:insoluble

SECTION 10: Stability and Reactivity
Stability:air sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged contact with air.
Incompatibility:oxidizing agents
Decomposition Products:carbon dioxide, carbon monoxide, organic fumes, phosphorous pentoxide, and iridium compounds.

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn
Risk Phrases R36/37/38
Safety Phrases 26-36/37/39
RIDADR UN2813
Packaging Group III
Hazard Class 4.3

 Synonyms

HYDRIDOCARBONYLTRIS(TRIPHENYLPHOSPHINE)IRIDIUM (I)
Hydridocarbonyltris(triphenylphosphine)iridium(I)
Carbonyltris(triphenylphosphine)iridium(I) hydride
Tris(triphenylphosphine)iridium(I) Carbonyl Hydride
EINECS 241-282-7
MFCD00015525