6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine

Modify Date: 2025-11-27 17:43:36

6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine Structure
6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine structure
Common Name 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine
CAS Number 175136-61-5 Molecular Weight 219.06500
Density 1.386g/cm3 Boiling Point 351.5ºC at 760 mmHg
Molecular Formula C9H8Cl2O2 Melting Point 101ºC
MSDS N/A Flash Point 148.9ºC

 Names

This table lists Chinese names, IUPAC names and various aliases of this chemical substance.

Name 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine
Synonym More Synonyms

 Chemical & Physical Properties

This table shows physicochemical parameters including melting point, boiling point, density, solubility and optical rotation. Missing data is marked as N/A.

Density 1.386g/cm3
Boiling Point 351.5ºC at 760 mmHg
Melting Point 101ºC
Molecular Formula C9H8Cl2O2
Molecular Weight 219.06500
Flash Point 148.9ºC
Exact Mass 217.99000
PSA 18.46000
LogP 2.94530
Vapour Pressure 8.31E-05mmHg at 25°C
Index of Refraction 1.567
InChIKey VEWSVLVKOXZHGM-UHFFFAOYSA-N
SMILES ClCc1cc(Cl)cc2c1OCOC2

 MSDS

This table provides MSDS information including hazard classification, first‑aid, fire‑fighting, spill handling, operation and storage instructions.

Name: 6-Chloro-8-(chloromethyl)-4h-1 3-benzodioxine 97% Material Safety Data Sheet
Synonym: 6-Chloro-8-chloromethylbenzo-1,3-dioxin
CAS: 175136-61-5
Section 1 - Chemical Product MSDS Name:6-Chloro-8-(chloromethyl)-4h-1 3-benzodioxine 97% Material Safety Data Sheet
Synonym:6-Chloro-8-chloromethylbenzo-1,3-dioxin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
175136-61-5 6-Chloro-8-(chloromethyl)-4H-1,3-benzo 97% unlisted
Hazard Symbols: C
Risk Phrases: 34

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Corrosives area.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 175136-61-5: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 99 - 101 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C9H8Cl2O2
Molecular Weight: 219

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, bases.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 175136-61-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
6-Chloro-8-(chloromethyl)-4H-1,3-benzodioxine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.*
Hazard Class: 8
UN Number: 3261
Packing Group: III
IMO
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing Group: III
RID/ADR
Shipping Name: CORROSIVE SOLID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8
UN Number: 3261
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 175136-61-5: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 175136-61-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 175136-61-5 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

This table covers safety warnings, protective measures, incompatible substances and disposal guidelines for this compound.

Risk Phrases R36/37/38
Safety Phrases S26
HS Code 2932999099

 Synthetic Route

This table presents publicly reported synthetic routes, reaction conditions, reactants and product information of the compound.

~%

6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine Structure

6-chloro-8-(chl...

CAS#:175136-61-5

Learn More
Literature: Journal of the American Chemical Society, , vol. 62, p. 890,891

~%

6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine Structure

6-chloro-8-(chl...

CAS#:175136-61-5

Learn More
Literature: Chemische Berichte, , vol. 77/79, p. 731,734

 Customs

This table shows customs‑related data including HS‑code, tariff and regulatory conditions for import and export.

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

This table collects all English aliases, systematic names and CAS‑related synonyms of the compound.

6-chloro-8-chloromethyl-4H-benzo[1,3]dioxin
6-CHLORO-8-CHLOROMETHYLBENZO-1,3-DIOXANE
6-Chlor-8-chlormethyl-4H-benzo[1,3]dioxin
BB_SC-5957

  | FAQ

This section contains frequently‑asked‑questions about this compound, including basic parameters, properties, storage conditions and corresponding answers.

Q: What is the SMILES notation of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: SMILES notation of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine is ClCc1cc(Cl)cc2c1OCOC2.
Q: What is the boiling point of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: Boiling point of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine is 351.5ºC at 760 mmHg.
Q: What is the polar surface area (PSA) of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: Polar surface area (PSA) of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine is 18.46000.
Q: What is the safety information for 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: Safety information for 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine: S26.
Q: What is the melting point of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: Melting point of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine is 101ºC.
Q: What are the downstream products of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: Related downstream products(CAS) of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine: 111870-27-0;63944-31-0;860184-93-6;860185-06-4.
Q: What is the InChIKey of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: InChIKey of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine is VEWSVLVKOXZHGM-UHFFFAOYSA-N.
Q: What is the molecular formula of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: Molecular formula of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine is C9H8Cl2O2.
Q: What is the English name of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: The English name of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine is 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine.
Q: What is the CAS number of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine?
A: CAS number of 6-chloro-8-(chloromethyl)-4H-1,3-benzodioxine is 175136-61-5.

 factory

This table lists manufacturers and suppliers of this compound, including vendor names and product supply reference information.

Shanghai Nianxing Industrial Co., Ltd
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