Phenylphosphinic acid structure
|
Common Name | Phenylphosphinic acid | ||
---|---|---|---|---|
CAS Number | 1779-48-2 | Molecular Weight | 142.092 | |
Density | N/A | Boiling Point | 285.1±23.0 °C at 760 mmHg | |
Molecular Formula | C6H7O2P | Melting Point | 83-85 °C(lit.) | |
MSDS | Chinese USA | Flash Point | 126.2±22.6 °C | |
Symbol |
GHS05, GHS07 |
Signal Word | Danger |
Use of Phenylphosphinic acidPhenylphosphinic acid is an additive used with Noyori's catalyst for oxidation of sulfides to sulfones. |
Name | Phenylphosphinic acid |
---|---|
Synonym | More Synonyms |
Boiling Point | 285.1±23.0 °C at 760 mmHg |
---|---|
Melting Point | 83-85 °C(lit.) |
Molecular Formula | C6H7O2P |
Molecular Weight | 142.092 |
Flash Point | 126.2±22.6 °C |
Exact Mass | 142.018372 |
PSA | 60.77000 |
LogP | -0.59 |
Vapour Pressure | 0.0±0.6 mmHg at 25°C |
Water Solubility | 7.7 g/100 mL (25 ºC) |
CHEMICAL IDENTIFICATION
HEALTH HAZARD DATAACUTE TOXICITY DATA
|
Symbol |
GHS05, GHS07 |
---|---|
Signal Word | Danger |
Hazard Statements | H302-H314 |
Precautionary Statements | P280-P305 + P351 + P338-P310 |
Personal Protective Equipment | Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges |
Hazard Codes | C:Corrosive;Xn:Harmful; |
Risk Phrases | R22;R34;R37/38;R41 |
Safety Phrases | S26-S36/37/39-S45 |
RIDADR | UN 3261 8/PG 3 |
WGK Germany | 3 |
RTECS | SZ5462500 |
Packaging Group | III |
Hazard Class | 8 |
HS Code | 2916399090 |
Precursor 10 | |
---|---|
DownStream 10 | |
HS Code | 2916399090 |
---|---|
Summary | 2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0% |
1H-17O nuclear quadrupole double resonance in phenylphosphinic acid and phenylphosphonic acid. 17O quadrupole coupling in P = O and P-O-H bonds.
Magn. Reson. Chem. 46(10) , 969-73, (2008) The (17)O nuclear quadrupole resonance (NQR) frequencies have been measured in phenylphosphinic acid and phenylphosphonic acid using nuclear quadrupole double resonance. The quadrupole coupling consta... |
|
First principles NMR calculations of phenylphosphinic acid C6H5HPO(OH): assignments, orientation of tensors by local field experiments and effect of molecular motion.
J. Magn. Reson. 187(1) , 131-40, (2007) The complete set of NMR parameters for (17)O enriched phenylphosphinic acid C(6)H(5)HP( *)O(*OH) is calculated from first principles by using the Gauge Including Projected Augmented Wave (GIPAW) appro... |
|
Photophysical and structural impact of phosphorylated anions associated to lanthanide complexes in water.
Inorg. Chem. 44(20) , 7151-60, (2005) A new ligand, LC, bis-[(6'-carboxy-2,2'-bipyridine-6-yl)]phenylphosphine oxide, in which the tridentate 6-carboxy-2,2'-bipyridyl arms are directly linked to a phenylphosphine oxide fragment, has been ... |
Phosphonousacid,phenyl |
phenyl-phosphinicaci |
Phosphinicacid,phenyl |
Phosphinic acid, P-phenyl- |
Hydroxyphenylphosphine oxide |
MFCD00002131 |
Phosphinic acid, phenyl- |
Phenylphosphinic acid |
phenyl-H-phosphinic acid |
phenyl phosphinic acid |
PHENYLPHOSPHONOUS ACID |
phenylphospho acid |
Benzenephosphonous Acid |
Coproporphyrin I-15N4 |
EINECS 217-217-3 |
Benzenephosphinic acid |