2-(2-Bromoethyl)-1,3-dioxolane

Modify Date: 2024-01-02 20:47:18

2-(2-Bromoethyl)-1,3-dioxolane Structure
2-(2-Bromoethyl)-1,3-dioxolane structure
Common Name 2-(2-Bromoethyl)-1,3-dioxolane
CAS Number 18742-02-4 Molecular Weight 181.028
Density 1.5±0.1 g/cm3 Boiling Point 200.9±15.0 °C at 760 mmHg
Molecular Formula C5H9BrO2 Melting Point N/A
MSDS Chinese USA Flash Point 85.0±0.0 °C
Symbol GHS06
GHS06
Signal Word Danger

 Names

Name 2-(2-Bromoethyl)-1,3-dioxolane
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.5±0.1 g/cm3
Boiling Point 200.9±15.0 °C at 760 mmHg
Molecular Formula C5H9BrO2
Molecular Weight 181.028
Flash Point 85.0±0.0 °C
Exact Mass 179.978592
PSA 18.46000
LogP 0.57
Vapour Pressure 0.4±0.4 mmHg at 25°C
Index of Refraction 1.473
Storage condition 2-8°C
Water Solubility immiscible

 Safety Information

Symbol GHS06
GHS06
Signal Word Danger
Hazard Statements H301-H315-H319-H335
Precautionary Statements P261-P301 + P310-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26-S37/39
RIDADR UN 2810 6.1/PG 3
WGK Germany 2
HS Code 2932999099

 Synthetic Route

~58%

2-(2-Bromoethyl)-1,3-dioxolane Structure

2-(2-Bromoethyl...

CAS#:18742-02-4

Literature: Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 36, # 4 p. 833 - 837 Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 4 p. 906 - 910

~53%

2-(2-Bromoethyl)-1,3-dioxolane Structure

2-(2-Bromoethyl...

CAS#:18742-02-4

Literature: Synthetic Communications, , vol. 15, # 2 p. 87 - 90

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles13

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Suzuki-Miyaura cross-coupling of potassium dioxolanylethyltrifluoroborate and aryl/heteroaryl chlorides.

Org. Lett. 15(7) , 1536-9, (2013)

A robust and efficient protocol for the introduction of the dioxolanylethyl moiety onto various aryl and heteroaryl halides has been developed, providing cross-coupling yields up to 93%. Copper-cataly...

Facile syntheses for (5Z,9Z)-5,9-hexadecadienoic acid, (5Z,9Z)-5,9-nonadecadienoic acid, and (5Z,9Z)-5,9-eicosadienoic acid through a common synthetic route.

Chem. Phys. Lipids 100(1-2) , 33-40, (1999)

The delta 5,9 fatty acids (5Z,9Z)-5,9-hexadecadienoic acid, (5Z,9Z)-5,9-nonadecadienoic acid, and (5Z,9Z)-5,9-eicosadienoic acid were synthesized for the first time in four steps (9-12% overall yield)...

Tetrahedron Lett. 34 , 6411, (1993)

 Synonyms

2-(2'-bromoethyl)-1,3-dioxolane
1-bromo-3-(1,3-dioxolane)-n-propane
2-(-bromoethyl)-1,3-dioxolane
2,7-DICHLOROFLUORENYL-4-ETHYLENE OXIDE
1,3-Dioxolane,2-(2-bromoethyl)
1-(1,3-dioxolan-2-yl)-2-bromoethane
3-Bromopropionaldehyde Ethylene Acetal
2-(1,3-dioxolan-2-yl)ethyl bromide
MFCD00003216
2-(2-Bromoethyl)-1,3-dioxolane
EINECS 242-551-1
1,3-Dioxolane, 2-(2-bromoethyl)-
2-(1,3-dioxa-2-cyclopentyl)-ethyl bromide
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