Lithium tert-butoxide

Modify Date: 2024-01-03 17:40:24

Lithium tert-butoxide Structure
Lithium tert-butoxide structure
Common Name Lithium tert-butoxide
CAS Number 1907-33-1 Molecular Weight 80.055
Density 0.89 g/mL at 20 °C Boiling Point 68-70 °C
Molecular Formula C4H9LiO Melting Point °C
MSDS Chinese USA Flash Point −2 °F
Symbol GHS02 GHS05 GHS07 GHS08
GHS02, GHS05, GHS07, GHS08
Signal Word Danger

 Names

Name Lithium tert-butoxide
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.89 g/mL at 20 °C
Boiling Point 68-70 °C
Melting Point °C
Molecular Formula C4H9LiO
Molecular Weight 80.055
Flash Point −2 °F
Exact Mass 80.081345
PSA 23.06000
LogP 1.21540
Index of Refraction 1.52299 (124ºC)
Storage condition Flammables area
Water Solubility vigorous reaction

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UB8520000
CHEMICAL NAME :
2-Propanol, 2-methyl-, lithium salt
CAS REGISTRY NUMBER :
1907-33-1
LAST UPDATED :
199712
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C4-H9-O.Li

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1682 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
TOVEFN Toksikologicheskii Vestnik. (18-20 Vadkovskii per. Moscow, 101479, Russia) History Unknown Volume(issue)/page/year: (3),37,1996

 Safety Information

Symbol GHS02 GHS05 GHS07 GHS08
GHS02, GHS05, GHS07, GHS08
Signal Word Danger
Hazard Statements H225-H251-H302-H314-H335-H351
Supplemental HS May form explosive peroxides., Reacts violently with water.
Precautionary Statements P210-P280-P370 + P378-P403 + P235-P407-P413
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;C:Corrosive;
Risk Phrases R11;R14;R35
Safety Phrases S26-S36/37/39-S45-S61-S62-S6A-S43E-S16-S7/8-S43-S33
RIDADR UN 3206 4.2/PG 2
WGK Germany 3
RTECS UB8520000
Packaging Group III
Hazard Class 4.2
HS Code 2905143000

 Synthetic Route

 Customs

HS Code 2915900090
Summary 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

 Articles1

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 Synonyms

2-Propanol, 2-methyl-, lithium salt (1:1)
Lithium t-butoxide
Lithium 2-methyl-2-propanolate
Lithium tert-butoxide
Lithium tertiary butoxide
Lithiumtert-butoxid
MFCD00050479
EINECS 217-611-5
tert-butoxylithium
t-butoxylithium
LTB
LITHIUM-TERT.-BUTYLAT
lithiumtert-butanolate
Lithium 2-methylpropan-2-olate
LITHIUM TERT-BUTYLATE
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