1,2-Dipiperidinylethane

Modify Date: 2024-01-11 19:34:04

1,2-Dipiperidinylethane Structure
1,2-Dipiperidinylethane structure
Common Name 1,2-Dipiperidinylethane
CAS Number 1932-04-3 Molecular Weight 196.33200
Density N/A Boiling Point N/A
Molecular Formula C12H24N2 Melting Point -1--0.5 ℃
MSDS N/A Flash Point N/A

 Names

Name 1-(2-piperidin-1-ylethyl)piperidine
Synonym More Synonyms

 Chemical & Physical Properties

Melting Point -1--0.5 ℃
Molecular Formula C12H24N2
Molecular Weight 196.33200
Exact Mass 196.19400
PSA 6.48000
LogP 1.83400
Vapour Pressure 0.0094mmHg at 25°C

 MSDS

Name: 1 2-Dipiperidinoethane 98% Material Safety Data Sheet
Synonym: 1,1'-(1,2-Ethanediyl)bispiperidin
CAS: 1932-04-3
Section 1 - Chemical Product MSDS Name:1 2-Dipiperidinoethane 98% Material Safety Data Sheet
Synonym:1,1'-(1,2-Ethanediyl)bispiperidin

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
1932-04-3 1,2-Dipiperidinoethane 98 217-692-7
Hazard Symbols: XI
Risk Phrases: 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.Hygroscopic (absorbs moisture from the air).The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation. Do not get water inside containers.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage:
Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 1932-04-3: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Liquid
Color: yellow
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 265 deg C @ 760.00mmHg
Freezing/Melting Point: 1 deg C
Autoignition Temperature: Not available.
Flash Point: 110 deg C ( 230.00 deg F)
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: .9160g/cm3
Molecular Formula: C12H24N2
Molecular Weight: 196.33

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, moisture, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
Hazardous Polymerization: Has not been reported.

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 1932-04-3 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,2-Dipiperidinoethane - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 1932-04-3: No information available.
Canada
CAS# 1932-04-3 is listed on Canada's NDSL List.
CAS# 1932-04-3 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1932-04-3 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi
Risk Phrases 36/37/38
Safety Phrases 24/25
HS Code 2933399090

 Synthetic Route

~87%

1,2-Dipiperidinylethane Structure

1,2-Dipiperidin...

CAS#:1932-04-3

Literature: Gamzaeva; Mamedova, P. Sh.; Allakhverdieva; Velieva, G. Kh.; Akhundova; Allakhverdiev Russian Journal of Applied Chemistry, 2009 , vol. 82, # 9 p. 1577 - 1581

~79%

1,2-Dipiperidinylethane Structure

1,2-Dipiperidin...

CAS#:1932-04-3

Literature: Katritzky, Alan R.; Fan, Wei-Qiang; Fu, Cong Journal of Organic Chemistry, 1990 , vol. 55, # 10 p. 3209 - 3213

~86%

1,2-Dipiperidinylethane Structure

1,2-Dipiperidin...

CAS#:1932-04-3

Literature: Zhao, Yaohong; Cai, Shunyou; Li, Jing; Wang, David Zhigang Tetrahedron, 2013 , vol. 69, # 38 p. 8129 - 8131

~%

1,2-Dipiperidinylethane Structure

1,2-Dipiperidin...

CAS#:1932-04-3

Literature: Miyahara; Sueyoshi; Kamiya Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 12 p. 5557 - 5561

~35%

1,2-Dipiperidinylethane Structure

1,2-Dipiperidin...

CAS#:1932-04-3

Literature: Miyahara; Sueyoshi; Kamiya Chemical and Pharmaceutical Bulletin, 1985 , vol. 33, # 12 p. 5557 - 5561

~%

1,2-Dipiperidinylethane Structure

1,2-Dipiperidin...

CAS#:1932-04-3

Literature: Bitsi, G.; Schleiffer, E.; Antoni, F.; Jenner, G. Journal of Organometallic Chemistry, 1989 , vol. 373, p. 343 - 352

~%

1,2-Dipiperidinylethane Structure

1,2-Dipiperidin...

CAS#:1932-04-3

Literature: Ladenburg Chemische Berichte, 1892 , vol. 25, p. 2792

~%

1,2-Dipiperidinylethane Structure

1,2-Dipiperidin...

CAS#:1932-04-3

Literature: Knorr; Hoerlein; Roth Chemische Berichte, 1905 , vol. 38, p. 3138

 Customs

HS Code 2933399090
Summary 2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

1,2-bispiperidinoethane
1,1'-Ethylenedipiperidine
EINECS 217-692-7
1,2-Dipiperidinylethane
1,2-di(N-piperidine)ethane
Dipiperidinoethane
1,2-Dipiperidinoethane
N,N'-1,2-dipiperidinoethane
Piperidine,1'-ethylenedi
1-[2-(piperidin-1-yl)ethyl]piperidine
N,N'-dipiperidylethane
1,1'-(1,2-Ethanediyl)bispiperidine
1,2-di(piperidin-1-yl)ethane
Piperidine,1,1'-(1,2-ethanediyl)bis