(4R,5R)-(-)-2,2-DIMETHYL-A,A,A',A'-TETRA(1-NAPHTHYL)-1,3-DIOXOLANE-4,5-DIMETHANOLATOTITANIUM(IV) DICHLORIDE ACETONITRILE ADDUCT

EINECS Number:none
Chemical Family:organometallic complex
Synonym:Titanium naphthylTADDOL

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Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound197389-47-2100%no datano data

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Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. With moisture, may liberate fumes of hydrogen chloride.
Primary Routes of Exposure:Inhalation, skin, eyes.
Eye Contact:Dust and vapors cause moderate irritation of the eyes.
Skin Contact:Causes moderate irritation of the skin.
Inhalation:Inhalation of dust or fumes causes irritation to the nose, mucous membranes and respiratory tract.
Ingestion:No information is available on the physiological effects of ingestion.
Irritation to skin, eyes, mucous membranes and respiratory tract. Exposure to moisture slowly produces
Acute Health Affects:
hydrochloric acid.
Chronic Health Affects:No information available on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:none
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:carbon dioxide, dry powder or foam
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit toxic fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

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SECTION 7: Handling and Storage
Store material in a tightly sealed bottle, preferably under an inert atmosphere. If possible, handle material in an
Handling and Storage:
efficient fume hood. Prolonged exposure to the atmosphere will lead to degradation of the product.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective gloves.
Ventilation:If possible, handle the material in an efficient fume hood.
No respirator is required when handling this material unless large volumes are handled in a poorly ventilated
Respirator:
area.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:Yellow powder
Molecular Weight:783.58(824.63)
Melting Point:no data
Boiling Point:decomposes
Vapor Pressure:no data
Specific Gravity:no data
Odor:may have an acidic odor.
Solubility in Water:reacts with water

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SECTION 10: Stability and Reactivity
Stability:Moisture-sensitive solid
Hazardous Polymerization:none
Conditions to Avoid:material may absorb water from the atmosphere on prolonged exposure.
Incompatibility:water, alcohols, reactive metals
Decomposition Products:Carbon dioxide, carbon monoxide, hydrogen chloride, titanium oxide, and organic vapors.

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SECTION 11: Toxicological Information
RTECS Data:No specific information available from the RTECS files.
Carcinogenic Effects:No data available
Mutagenic Effects:No data available
Tetratogenic Effects:No data available

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SECTION 12: Ecological Information
Ecological Information:No information available

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SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Non hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

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SECTION 15: Regulatory Information
TSCA:not listed in the TSCA inventory
SARA (Title 313):not reportable under SARA Title 13
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A