[1R-(1alpha,2beta,4beta,6alpha)]-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane structure
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Common Name | [1R-(1alpha,2beta,4beta,6alpha)]-2,2,7-trimethyl-3-oxatricyclo[4.1.1.02,4]octane | ||
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CAS Number | 19894-99-6 | Molecular Weight | 152.23300 | |
Density | 1.027g/cm3 | Boiling Point | 188.6ºC at 760mmHg | |
Molecular Formula | C10H16O | Melting Point | N/A | |
MSDS | N/A | Flash Point | 65.6ºC |
Name | L-α-(-)-PINENE OXIDE |
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Synonym | More Synonyms |
Density | 1.027g/cm3 |
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Boiling Point | 188.6ºC at 760mmHg |
Molecular Formula | C10H16O |
Molecular Weight | 152.23300 |
Flash Point | 65.6ºC |
Exact Mass | 152.12000 |
PSA | 12.53000 |
LogP | 2.20990 |
Vapour Pressure | 0.819mmHg at 25°C |
Index of Refraction | 1.504 |
Synonym:3-Oxatricyclo[4.1.1.02,4]octane, 2,7,7-trimethyl-, (1R,2R,4S,6R)-; 3-Oxatricyclo[4.1.1.02,4]octane, 2,7,7-trimethyl-, [1R-(1alpha,2beta,4beta,6alpha)]-; Pinane, 2,3-epoxy-, (1R,2R,3S,5R)-(-)- Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 10 37/38 41 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Flammable. Irritating to respiratory system and skin. Risk of serious damage to eyes. Potential Health Effects Eye: Causes severe eye irritation and possible burns. Skin: Causes skin irritation. Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. Ingestion of large amounts may cause central nervous depression. Inhalation: Causes respiratory tract irritation. Chronic: Effects may be delayed. Section 4 - FIRST AID MEASURES Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. Notes to Physician: Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode when heated. Runoff from fire control or dilution water may cause pollution. Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Use agent most appropriate to extinguish fire. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Section 7 - HANDLING and STORAGE Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Storage: Keep away from sources of ignition. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 19894-99-6: CAS# 72936-74-4: Personal Protective Equipment Eyes: Wear chemical splash goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: clear, colorless Odor: camphor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: 192 deg C Freezing/Melting Point: Not available. Autoignition Temperature: Not applicable. Flash Point: 55 deg C ( 131.00 deg F) Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Negligible. Specific Gravity/Density: .9640g/cm3 Molecular Formula: C10H16O Molecular Weight: 152.24 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Stable under normal temperatures and pressures. Conditions to Avoid: Ignition sources, excess heat. Incompatibilities with Other Materials: Oxidizing agents, strong acids, strong bases. Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 19894-99-6 unlisted. CAS# 72936-74-4 unlisted. LD50/LC50: Not available. Not available. Carcinogenicity: (-)-alpha-Pinene oxide - Not listed by ACGIH, IARC, or NTP. Epoxypinene - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA Not regulated as a hazardous material. IMO Not regulated as a hazardous material. RID/ADR Shipping Name: Not regulated. Hazard Class: UN Number: Packing group: Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 10 Flammable. R 37/38 Irritating to respiratory system and skin. R 41 Risk of serious damage to eyes. Safety Phrases: S 16 Keep away from sources of ignition - No smoking. S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 19894-99-6: No information available. CAS# 72936-74-4: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 19894-99-6 is not listed on Canada's Ingredient Disclosure List. CAS# 72936-74-4 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 19894-99-6 is not listed on the TSCA inventory. It is for research and development use only. CAS# 72936-74-4 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi:Irritant; |
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Risk Phrases | R10;R37/38;R41 |
Safety Phrases | S16-S26-S37/39 |
EINECS 243-411-2 |
2-Phenylbutyric anhydride |
2-Phenylbutyric acid anhydride |
rac-2-phenylbutanoic acid anhydride |
2-phenylbutanoic anhydride |
epoxy-orthodene |
MFCD00066955 |