Bis(2-methoxyethyl)aminosulphur trifluoride

Modify Date: 2024-01-02 06:26:04

Bis(2-methoxyethyl)aminosulphur trifluoride Structure
Bis(2-methoxyethyl)aminosulphur trifluoride structure
Common Name Bis(2-methoxyethyl)aminosulphur trifluoride
CAS Number 202289-38-1 Molecular Weight 221.241
Density 1.2±0.1 g/cm3 Boiling Point 256.3±25.0 °C at 760 mmHg
Molecular Formula C6H14F3NO2S Melting Point N/A
MSDS Chinese USA Flash Point 108.8±23.2 °C
Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
Signal Word Danger

 Names

Name 2-methoxy-N-(2-methoxyethyl)-N-(trifluoro-λ4-sulfanyl)ethanamine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 256.3±25.0 °C at 760 mmHg
Molecular Formula C6H14F3NO2S
Molecular Weight 221.241
Flash Point 108.8±23.2 °C
Exact Mass 221.069733
PSA 47.00000
LogP 1.95430
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.392
Storage condition 2-8°C

 Safety Information

Symbol GHS02 GHS05 GHS06
GHS02, GHS05, GHS06
Signal Word Danger
Hazard Statements H261-H301-H314-H331
Supplemental HS Contact with water liberates toxic gas., Reacts violently with water.
Precautionary Statements P231 + P232-P261-P280-P301 + P310-P305 + P351 + P338-P422
Personal Protective Equipment Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;T:Toxic;
Risk Phrases R11;R14;R25;R35;R48/20;R63;R65;R67
Safety Phrases 23-26-36/37/39-43-45-8-62-46-25-16
RIDADR UN REST
WGK Germany 3

 Synthetic Route

~71%

Bis(2-methoxyethyl)aminosulphur trifluoride Structure

Bis(2-methoxyet...

CAS#:202289-38-1

Literature: Chemical Communications, , # 2 p. 215 - 216

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Bis(2-methoxyethyl)aminosulphur trifluoride Structure

Bis(2-methoxyet...

CAS#:202289-38-1

Literature: Journal of Organic Chemistry, , vol. 64, # 19 p. 7048 - 7054

 Articles6

More Articles
[Bis(2-methoxyethyl)amino]sulfur trifluoride, the Deoxo-Fluor reagent: application toward one-flask transformations of carboxylic acids to amides.

J. Org. Chem. 69 , 2573, (2004)

The use of the Deoxo-Fluor reagent is a versatile method for acyl fluoride generation and subsequent one-flask amide coupling. It provides mild conditions and facile purification of the desired produc...

Fluorination of thiocarbonyl compounds with Bis(2-methoxyethyl)aminosulfur trifluoride (Deoxo-fluor reagent): A facile synthesis of gem-difluorides

J. Org. Chem. 65 , 4830, (2000)

A variety of thiocarbonyl derivatives (thioketone, thioester, thioamide, dithioester, and dithiocarbamate) were converted to the corresponding gem-difluorides in excellent yields on reaction with the ...

One-pot route to new alpha,alpha-difluoroamides and alpha-ketoamides.

J. Org. Chem. 68 , 6063, (2003)

New alpha,alpha-difluoroamides (4a-d, 6a-d) and alpha-ketoamides (5a-d, 7a-d) result from one-pot reactions of alpha-ketoacids, RCOCO(2)H (R = C(6)H(5), CH(3), CH(3)CH(2), thienyl) (1a-d) with bis(2-m...

 Synonyms

DeoxofluorTM
MFCD01321415
UNII-A6219390VZ
2-Methoxy-N-(2-methoxyethyl)-N-(trifluoro-λ-sulfanyl)ethanamine
diethylaminosulfur trifluoride
2-Methoxy-N-(2-methoxyethyl)-N-(trifluorothio)-ethanamine
Sulfur, [bis(2-methoxyethyl)amino]trifluoro-
Bis-(2-methoxyethyl)aminosulfur trifluoride
Deoxo-Fluor solution
EINECS 478-190-3
Deoxo-Fluor
[Bis(2-methoxyethyl)amino]sulfur trifluoride,2.7M
Bis(2-methoxyethyl)aminosulphur trifluoride
BAST
Bis(2-methoxyethyl)aminosulfur trifluoride