Bis(2-methoxyethyl)aminosulphur trifluoride structure
|
Common Name | Bis(2-methoxyethyl)aminosulphur trifluoride | ||
---|---|---|---|---|
CAS Number | 202289-38-1 | Molecular Weight | 221.241 | |
Density | 1.2±0.1 g/cm3 | Boiling Point | 256.3±25.0 °C at 760 mmHg | |
Molecular Formula | C6H14F3NO2S | Melting Point | N/A | |
MSDS | Chinese USA | Flash Point | 108.8±23.2 °C | |
Symbol |
GHS02, GHS05, GHS06 |
Signal Word | Danger |
Name | 2-methoxy-N-(2-methoxyethyl)-N-(trifluoro-λ4-sulfanyl)ethanamine |
---|---|
Synonym | More Synonyms |
Density | 1.2±0.1 g/cm3 |
---|---|
Boiling Point | 256.3±25.0 °C at 760 mmHg |
Molecular Formula | C6H14F3NO2S |
Molecular Weight | 221.241 |
Flash Point | 108.8±23.2 °C |
Exact Mass | 221.069733 |
PSA | 47.00000 |
LogP | 1.95430 |
Vapour Pressure | 0.0±0.5 mmHg at 25°C |
Index of Refraction | 1.392 |
Storage condition | 2-8°C |
Symbol |
GHS02, GHS05, GHS06 |
---|---|
Signal Word | Danger |
Hazard Statements | H261-H301-H314-H331 |
Supplemental HS | Contact with water liberates toxic gas., Reacts violently with water. |
Precautionary Statements | P231 + P232-P261-P280-P301 + P310-P305 + P351 + P338-P422 |
Personal Protective Equipment | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
Hazard Codes | F:Flammable;T:Toxic; |
Risk Phrases | R11;R14;R25;R35;R48/20;R63;R65;R67 |
Safety Phrases | 23-26-36/37/39-43-45-8-62-46-25-16 |
RIDADR | UN REST |
WGK Germany | 3 |
~71% Bis(2-methoxyet... CAS#:202289-38-1 |
Literature: Chemical Communications, , # 2 p. 215 - 216 |
~% Bis(2-methoxyet... CAS#:202289-38-1 |
Literature: Journal of Organic Chemistry, , vol. 64, # 19 p. 7048 - 7054 |
[Bis(2-methoxyethyl)amino]sulfur trifluoride, the Deoxo-Fluor reagent: application toward one-flask transformations of carboxylic acids to amides.
J. Org. Chem. 69 , 2573, (2004) The use of the Deoxo-Fluor reagent is a versatile method for acyl fluoride generation and subsequent one-flask amide coupling. It provides mild conditions and facile purification of the desired produc... |
|
Fluorination of thiocarbonyl compounds with Bis(2-methoxyethyl)aminosulfur trifluoride (Deoxo-fluor reagent): A facile synthesis of gem-difluorides
J. Org. Chem. 65 , 4830, (2000) A variety of thiocarbonyl derivatives (thioketone, thioester, thioamide, dithioester, and dithiocarbamate) were converted to the corresponding gem-difluorides in excellent yields on reaction with the ... |
|
One-pot route to new alpha,alpha-difluoroamides and alpha-ketoamides.
J. Org. Chem. 68 , 6063, (2003) New alpha,alpha-difluoroamides (4a-d, 6a-d) and alpha-ketoamides (5a-d, 7a-d) result from one-pot reactions of alpha-ketoacids, RCOCO(2)H (R = C(6)H(5), CH(3), CH(3)CH(2), thienyl) (1a-d) with bis(2-m... |
DeoxofluorTM |
MFCD01321415 |
UNII-A6219390VZ |
2-Methoxy-N-(2-methoxyethyl)-N-(trifluoro-λ-sulfanyl)ethanamine |
diethylaminosulfur trifluoride |
2-Methoxy-N-(2-methoxyethyl)-N-(trifluorothio)-ethanamine |
Sulfur, [bis(2-methoxyethyl)amino]trifluoro- |
Bis-(2-methoxyethyl)aminosulfur trifluoride |
Deoxo-Fluor solution |
EINECS 478-190-3 |
Deoxo-Fluor |
[Bis(2-methoxyethyl)amino]sulfur trifluoride,2.7M |
Bis(2-methoxyethyl)aminosulphur trifluoride |
BAST |
Bis(2-methoxyethyl)aminosulfur trifluoride |