6-bromo-1,8-naphthalicanhydride

Modify Date: 2024-01-04 18:15:49

6-bromo-1,8-naphthalicanhydride Structure
6-bromo-1,8-naphthalicanhydride structure
Common Name 6-bromo-1,8-naphthalicanhydride
CAS Number 21563-29-1 Molecular Weight 277.070
Density 1.8±0.1 g/cm3 Boiling Point 467.2±28.0 °C at 760 mmHg
Molecular Formula C12H5BrO3 Melting Point 217-219ºC
MSDS N/A Flash Point 236.3±24.0 °C

 Names

Name 4-Bromo-1,8-naphthalic anhydride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.8±0.1 g/cm3
Boiling Point 467.2±28.0 °C at 760 mmHg
Melting Point 217-219ºC
Molecular Formula C12H5BrO3
Molecular Weight 277.070
Flash Point 236.3±24.0 °C
Exact Mass 275.942200
PSA 43.37000
LogP 2.53
Vapour Pressure 0.0±1.2 mmHg at 25°C
Index of Refraction 1.733
Storage condition Room temperature.

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: 4-Bromo-1,8-naphthalic anhydride
Synonyms:6-Bromobenzo[de]isochromene-1,3-dione

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.
H315:Causes skin irritation
H319:Causes serious eye irritation
H335:May cause respiratory irritation
P261:Avoid breathing dust/fume/gas/mist/vapours/spray
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present
and easy to do – continue rinsing

Section3. Composition/information on ingredients.
Ingredient name:4-Bromo-1,8-naphthalic anhydride
CAS number:21563-29-1

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
Eye contact:
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Storage:Store in closed vessels.

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
No data
Boiling point:
Melting point:No data
Flash point:No data
Density:No data
Molecular formula: C12H5BrO3
Molecular weight: 277.1

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, hydrogen bromide.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases R36/37/38
Safety Phrases S26
WGK Germany 3
HS Code 2942000000

 Synthetic Route

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6-bromo-1,8-naphthalicanhydride Structure

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CAS#:21563-29-1

Literature: Chimija chim. Technol. (NDVS)Chem.Abstr., , p. 322 Chimija chim. Technol. (NDVS)Chem.Abstr., , p. 444

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6-bromo-1,8-naphthalicanhydride Structure

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CAS#:21563-29-1

Literature: Solodar', S. L.; Vinogradov, L. M. Journal of Organic Chemistry USSR (English Translation), 1980 , vol. 16, p. 1102 - 1104 Zhurnal Organicheskoi Khimii, 1980 , vol. 16, # 6 p. 1275 - 1277

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6-bromo-1,8-naphthalicanhydride Structure

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CAS#:21563-29-1

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 16, p. 1102 - 1104 Zhurnal Organicheskoi Khimii, , vol. 16, # 6 p. 1275 - 1277

~%

6-bromo-1,8-naphthalicanhydride Structure

6-bromo-1,8-nap...

CAS#:21563-29-1

Literature: Journal of Organic Chemistry USSR (English Translation), , vol. 16, p. 1102 - 1104 Zhurnal Organicheskoi Khimii, , vol. 16, # 6 p. 1275 - 1277

~%

6-bromo-1,8-naphthalicanhydride Structure

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CAS#:21563-29-1

Literature: Zhurnal Organicheskoi Khimii, , vol. 4, p. 1282 - 1286,1233 - 1236

 Customs

HS Code 2942000000

 Synonyms

2-bromo-1,8-naphthalic anhydride
4-BR0MO-1.8-NAPHTHALIC ANHYDRIDE
6-BROMO-BENZO[DE]ISOCHROMENE-1,3-DIONE
MFCD00006927
8-bromo-1,8-naphthalic anhydride
4-BROMO-1,8-NAPHTHALENEDICARBOXYLIC ANHYDRIDE
bromo-1,8 naphthalic anhydride
2-Bromnaphthalin-1,8-dicarbonsaeure
6-bromo-1H,3H-naphtho[1,8-cd]pyran-1,3-dione
6-Bromo-1H,3H-naphtho(1,8-cd)pyran-1,3-dione
1H,3H-Naphtho(1,8-cd)pyran-1,3-dione, 6-bromo-
1H,3H-Naphtho[1,8-cd]pyran-1,3-dione, 6-bromo-
4-Bromobenzo[de]isochromene-1,3-dione
2-bromonaphthalic anhydride
2-Brom-naphthalin-1,8-dicarbonsaeure-anhydrid
6-bromo-1,8-naphthalicanhydride
4-Bromonaphthalene-1,8-dicarboxylic anhydride
6-Bromo-1H,3H-benzo[de]isochromene-1,3-dione
2-bromo-naphthalene-1,8-dicarboxylic acid-anhydride
4-Bromo-1,8-naphthal
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