((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate

Modify Date: 2024-01-10 23:53:06

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate structure	Common Name	((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate
	CAS Number	23788-74-1	Molecular Weight	286.344
	Density	1.2±0.1 g/cm3	Boiling Point	400.1±25.0 °C at 760 mmHg
	Molecular Formula	C₁₃H₁₈O₅S	Melting Point	41-43 °C(lit.)
	MSDS	Chinese USA	Flash Point	195.8±23.2 °C

Name	[(4R)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl 4-methylbenzenesulfonate
Synonym	More Synonyms

Density	1.2±0.1 g/cm3
Boiling Point	400.1±25.0 °C at 760 mmHg
Melting Point	41-43 °C(lit.)
Molecular Formula	C₁₃H₁₈O₅S
Molecular Weight	286.344
Flash Point	195.8±23.2 °C
Exact Mass	286.087494
PSA	70.21000
LogP	1.58
Vapour Pressure	0.0±0.9 mmHg at 25°C
Index of Refraction	1.507
Storage condition	−20°C

MSDS(Chinese)

Personal Protective Equipment	dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes	Xn: Harmful;Xi: Irritant;
Risk Phrases	R36/37/38
Safety Phrases	S26-S36-S37/39
RIDADR	NONH for all modes of transport
WGK Germany	3
HS Code	2932999099

(S)-(+)-Solketal

CAS#:22323-82-6

Tosyl chloride

CAS#:98-59-9

~96%

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Dams, Iwona; Chodynski, Michal; Krupa, Malgorzata; Pietraszek, Anita; Zezula, Marta; Cmoch, Piotr; Kosinska, Monika; Kutner, Andrzej Tetrahedron, 2013 , vol. 69, # 5 p. 1634 - 1648

1,2:5,6-Bis-O-(...

CAS#:1707-77-3

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, , vol. 41, # 3 p. 586 - 592

Tosyl chloride

CAS#:98-59-9

(R)-(-)-Solketal

CAS#:14347-78-5

~93%

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Tsuda; Okada; Tanaka; Shigematsu; Hori; Goto; Hashimoto Chemical and Pharmaceutical Bulletin, 1991 , vol. 39, # 3 p. 607 - 611

(R)-(+)-2,2-Dim...

CAS#:15186-48-8

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Journal of Medicinal Chemistry, , vol. 27, # 9 p. 1142 - 1149

(S)-(+)-Solketal

CAS#:22323-82-6

~86%

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Tsuda, Yoshisuke; Yoshimoto, Kimihiro; Nishikawa, Terumi Chemical & Pharmaceutical Bulletin, 1981 , vol. 29, # 12 p. 3593 - 3600

Tosyl chloride

CAS#:98-59-9

1,2:5,6-Bis-O-(...

CAS#:1707-77-3

((R)-2,2-Dimeth...

CAS#:23788-74-1

Literature: Angewandte Chemie, , vol. 92, # 3 p. 201 - 202

Precursor 5
CAS#:22323-82-6 (S)-(+)-Solketal CAS#:98-59-9 Tosyl chloride CAS#:1707-77-3 1,2:5,6-Bis-O-(... CAS#:14347-78-5 (R)-(-)-Solketal
CAS#:15186-48-8 (R)-(+)-2,2-Dim...
DownStream 7
CAS#:41274-09-3 (R)-Glycerol 1-... CAS#:180959-54-0 4-[[(4S)-2,2-di... CAS#:72952-75-1 (S)-N-(2,2-DIME... CAS#:82954-65-2 (S)-(-)-PROPYLE...
CAS#:85820-82-2 2,2-dimethyl-4(... CAS#:4549-72-8 sodium,2-methyl... CAS#:506-03-6 1-O-Hexadecyl-s...

HS Code	2932999099
Summary	2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

C. André et al.

Tetrahedron Asymmetry 9 , 1359, (1998)

K.C. Nicolaou et al.

J. Chem. Soc. Chem. Commun. , 349, (1984)

S.K. Bhatia, J. Hajdu

Tetrahedron Lett. 28 , 1729, (1987)

(R)-(-)-2,2-dimethyl-4-tosyloxymethyl-1,3-dioxolane

(R)-(-)-2,2-dimethyl-4-(hydroxymethyl)-1,3-dioxolane-p-toluenesulfonate

(R)-2,2-dimethyl-1,3-dioxolan-4-methanol toluene-4-sulfonate

MFCD00063233

(R)-2,2-Dimethyl-1,3-dioxolane-4-methanol p-toluenesulfonate

[(4R)-2,2-Dimethyl-1,3-dioxolan-4-yl]methyl 4-methylbenzenesulfonate

1,3-Dioxolane-4-methanol, 2,2-dimethyl-, 4-methylbenzenesulfonate, (4R)-

(R)-2,2-dimethyl-[1,3]dioxolan-4-ylmethyl toluene-4-sulfonate

(R)-1-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl 4-methyl-benzenesulfonate

(4R)-2,2-dimethyl-4-(4-toluenesulphonyloxymethyl)-1,3-dioxolane

(R)-(2,2-dimethyl-1,3-dioxolan-4-yl)methyl 4-methylbenzenesulfonate

(R)-(-)-2,2-DIMETHYL-1,3-DIOXOLAN-4-YLMETHYL P-TOLUENESULFONATE

(R)-(-)-2,2-Dimethyl-1,3-dioxolan-4-ylmethylp-Toluenesulfonate

(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-ylmethyl-p-toluenesulfonate

(R)-2,2-dimethyl-1,3-dioxolan-4-ylmethyl p-tosylate

1,2-Isopropylidene-sn-glycerol 3-tosylate

(R)-(2,2-DIMETHYL-1,3-DIOXOLAN-4-YL)METHYL-4-METHYLBENZENESULFONATE

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate

p-Toluenesulfonic acid [(R)-2,2-dimethyl-1,3-dioxolane-4β-yl]methyl ester

((R)-2,2-Dimethyl-1,3-dioxolan-4-yl)methyl p-toluenesulfonate

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Chemical & Physical Properties

MSDS

Safety Information

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Precursor & DownStream

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Synonyms