Methyl 2-Amino-4-fluorobenzoate

Modify Date: 2024-01-14 12:03:54

Methyl 2-Amino-4-fluorobenzoate Structure
Methyl 2-Amino-4-fluorobenzoate structure
Common Name Methyl 2-Amino-4-fluorobenzoate
CAS Number 2475-81-2 Molecular Weight 169.15300
Density 1.264g/cm3 Boiling Point 255.5ºC at 760 mmHg
Molecular Formula C8H8FNO2 Melting Point N/A
MSDS N/A Flash Point 108.3ºC

 Names

Name Methyl 2-amino-4-fluorobenzoate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.264g/cm3
Boiling Point 255.5ºC at 760 mmHg
Molecular Formula C8H8FNO2
Molecular Weight 169.15300
Flash Point 108.3ºC
Exact Mass 169.05400
PSA 52.32000
LogP 1.77570
Vapour Pressure 0.0163mmHg at 25°C
Index of Refraction 1.544
Storage condition Room temperature.

 MSDS

Material Safety Data Sheet

Section1. Identification of the substance
Product Name: Methyl 2-amino-4-fluorobenzoate
Synonyms:

Section2. Hazards identification
Harmful by inhalation, in contact with skin, and if swallowed.

Section3. Composition/information on ingredients.
Ingredient name:Methyl 2-amino-4-fluorobenzoate
CAS number:2475-81-2

Section4. First aid measures
Skin contact:Immediately wash skin with copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. If irritation persists, seek medical attention.
Eye contact:Immediately wash skin with copious amounts of water for at least 15 minutes. Assure adequate
flushing of the eyes by separating the eyelids with fingers. If irritation persists, seek medical
attention.
Inhalation:Remove to fresh air. In severe cases or if symptoms persist, seek medical attention.
Ingestion:Wash out mouth with copious amounts of water for at least 15 minutes. Seek medical attention.

Section5. Fire fighting measures
In the event of a fire involving this material, alone or in combination with other materials, use dry
powder or carbon dioxide extinguishers. Protective clothing and self-contained breathing apparatus
should be worn.

Section6. Accidental release measures
Personal precautions: Wear suitable personal protective equipment which performs satisfactorily and meets local/state/national
standards.
Respiratory precaution:Wear approved mask/respirator
Hand precaution:Wear suitable gloves/gauntlets
Skin protection:Wear suitable protective clothing
Eye protection:Wear suitable eye protection
Methods for cleaning up: Mix with sand or similar inert absorbent material, sweep up and keep in a tightly closed container
for disposal. See section 12.
Environmental precautions: Do not allow material to enter drains or water courses.

Section7. Handling and storage
Handling:This product should be handled only by, or under the close supervision of, those properly qualified
in the handling and use of potentially hazardous chemicals, who should take into account the fire,
health and chemical hazard data given on this sheet.
Store in closed vessels.
Storage:

Section8. Exposure Controls / Personal protection
Engineering Controls: Use only in a chemical fume hood.
Personal protective equipment: Wear laboratory clothing, chemical-resistant gloves and safety goggles.
General hydiene measures: Wash thoroughly after handling. Wash contaminated clothing before reuse.

Section9. Physical and chemical properties
Appearance:Not specified
Boiling point:No data
No data
Melting point:
Flash point:No data
Density:No data
Molecular formula:C8H8FNO2
Molecular weight:169.2

Section10. Stability and reactivity
Conditions to avoid: Heat, flames and sparks.
Materials to avoid: Oxidizing agents.
Possible hazardous combustion products: Carbon monoxide, nitrogen oxides, hydrogen fluoride.

Section11. Toxicological information
No data.

Section12. Ecological information
No data.

Section13. Disposal consideration
Arrange disposal as special waste, by licensed disposal company, in consultation with local waste
disposal authority, in accordance with national and regional regulations.

Section14. Transportation information
Non-harzardous for air and ground transportation.

Section15. Regulatory information
No chemicals in this material are subject to the reporting requirements of SARA Title III, Section
302, or have known CAS numbers that exceed the threshold reporting levels established by SARA
Title III, Section 313.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

HS Code 2922499990

 Synthetic Route

~99%

Methyl 2-Amino-4-fluorobenzoate Structure

Methyl 2-Amino-...

CAS#:2475-81-2

Literature: MITENI S.p.A. Patent: WO2003/95417 A1, 2003 ; Location in patent: Page/Page column 7 ;

~97%

Methyl 2-Amino-4-fluorobenzoate Structure

Methyl 2-Amino-...

CAS#:2475-81-2

Literature: Halbrook, James; Kesicki, Edward A.; Burgess, Laurence E.; Schlachter, Stephen T.; Eary, Charles T.; Schiro, Justin G; Huang, Hongmei; Evans, Michael; Han, Yongxin Patent: US2002/165218 A1, 2002 ; US 20020165218 A1

~55%

Methyl 2-Amino-4-fluorobenzoate Structure

Methyl 2-Amino-...

CAS#:2475-81-2

Literature: GLAXOSMITHKLINE LLC; DAUGAN, Alain Claude-Marie; LAMOTTE, Yann; MIRGUET, Olivier Patent: WO2012/119978 A1, 2012 ; Location in patent: Page/Page column 50 ; WO 2012/119978 A1

~52%

Methyl 2-Amino-4-fluorobenzoate Structure

Methyl 2-Amino-...

CAS#:2475-81-2

Literature: Allison, Brett; McAtee, Laura C.; Phuong, Victor K.; Rabinowitz, Michael H.; Shankley, Nigel P. Patent: US2004/224983 A1, 2004 ; Location in patent: Page 28 ;

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Methyl 2-Amino-4-fluorobenzoate Structure

Methyl 2-Amino-...

CAS#:2475-81-2

Literature: US5093364 A1, ;

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Methyl 2-Amino-4-fluorobenzoate Structure

Methyl 2-Amino-...

CAS#:2475-81-2

Literature: US5599814 A1, ;

 Customs

HS Code 2922499990
Summary HS:2922499990 other amino-acids, other than those containing more than one kind of oxygen function, and their esters; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%

 Synonyms

methyl 4-fluoroanthranilate
methyl 2-amino-4-fluoro-benzoate
2-amino-4-fluoro-benzoic acid,methyl ester
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