2,6-Piperidinedione,4-methyl-

Modify Date: 2024-01-09 10:41:38

2,6-Piperidinedione,4-methyl- Structure
2,6-Piperidinedione,4-methyl- structure
 Common Name 2,6-Piperidinedione,4-methyl-
CAS Number 25077-26-3 Molecular Weight 127.14100
Density 1.101g/cm3 Boiling Point 277.9ºC at 760mmHg
Molecular Formula C6H9NO2 Melting Point N/A
MSDS N/A Flash Point 138.8ºC

 Names

Name 4-methylpiperidine-2,6-dione
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.101g/cm3
Boiling Point 277.9ºC at 760mmHg
Molecular Formula C6H9NO2
Molecular Weight 127.14100
Flash Point 138.8ºC
Exact Mass 127.06300
PSA 46.17000
LogP 0.38790
Vapour Pressure 0.00441mmHg at 25°C
Index of Refraction 1.455

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
MA5220020
CHEMICAL NAME :
Glutarimide, 3-methyl-
CAS REGISTRY NUMBER :
25077-26-3
BEILSTEIN REFERENCE NO. :
0114456
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C6-H9-N-O2
MOLECULAR WEIGHT :
127.16

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>600 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium) V.4- 1898- Volume(issue)/page/year: 173,115,1968

 Safety Information

HS Code 2925190090

 Synthetic Route

crotononitrile structure

crotononitrile

CAS#:4786-20-3

Methyl cyanoacetate structure

Methyl cyanoacetate

CAS#:105-34-0

~89%

2,6-Piperidinedione,4-methyl- Structure

2,6-Piperidined...

CAS#:25077-26-3

Literature: Takaya, Hikaru; Yoshida, Kazunori; Isozaki, Katsuhiro; Terai, Hiroki; Murahashi, Shun-Ichi Angewandte Chemie - International Edition, 2003 , vol. 42, # 28 p. 3302 - 3304
Methyl (2E)-2-butenoate structure

Methyl (2E)-2-b...

CAS#:623-43-8

Methyl cyanoacetate structure

Methyl cyanoacetate

CAS#:105-34-0

~67%

2,6-Piperidinedione,4-methyl- Structure

2,6-Piperidined...

CAS#:25077-26-3

Literature: Takaya, Hikaru; Yoshida, Kazunori; Isozaki, Katsuhiro; Terai, Hiroki; Murahashi, Shun-Ichi Angewandte Chemie - International Edition, 2003 , vol. 42, # 28 p. 3302 - 3304
Methyl (2E)-2-butenoate structure

Methyl (2E)-2-b...

CAS#:623-43-8

Iodoacetamide structure

Iodoacetamide

CAS#:144-48-9

~%

2,6-Piperidinedione,4-methyl- Structure

2,6-Piperidined...

CAS#:25077-26-3

methyl 3-acetamide-2-butyrate structure

methyl 3-acetam...

CAS#:102040-92-6

Literature: Sacripante, Guerino; Tan, Charles; Just, George Tetrahedron Letters, 1985 , vol. 26, # 46 p. 5643 - 5646
Methylglutaric acid structure

Methylglutaric acid

CAS#:626-51-7

~%

2,6-Piperidinedione,4-methyl- Structure

2,6-Piperidined...

CAS#:25077-26-3

Literature: Dabrowski, Zbigniew; Cybulski, Jacek Bulletin de l'Academie Polonaise des Sciences, Serie des Sciences Chimiques, 1981 , vol. 29, # 1-2 p. 11 - 16
ch3cho structure

ch3cho

CAS#:75-07-0

Cyanoacetic acid structure

Cyanoacetic acid

CAS#:372-09-8

~%

2,6-Piperidinedione,4-methyl- Structure

2,6-Piperidined...

CAS#:25077-26-3

Literature: Heim Bulletin des Societes Chimiques Belges, 1932 , vol. 41, p. 320,322
4-cyano-3-methyl-butyric acid ethyl ester structure

4-cyano-3-methy...

CAS#:33310-72-4

~%

2,6-Piperidinedione,4-methyl- Structure

2,6-Piperidined...

CAS#:25077-26-3

Literature: Takahashi; Kariyone Yakugaku Zasshi, 1959 , vol. 79, p. 711,716 Chem.Abstr., 1959 , p. 21940
D-3,7-dimethyl-oct-6-enenitrile structure

D-3,7-dimethyl-...

CAS#:35931-93-2

Acetone structure

Acetone

CAS#:67-64-1

~%

2,6-Piperidinedione,4-methyl- Structure

2,6-Piperidined...

CAS#:25077-26-3

5-Cyan-4-methyl-pentansaeure structure

5-Cyan-4-methyl...

CAS#:99356-87-3

Detail
Literature: Meluch; Mislow Journal of Organic Chemistry, 1955 , vol. 20, p. 1311,1314
Pyridine structure

Pyridine

CAS#:110-86-1

ch3cho structure

ch3cho

CAS#:75-07-0

Cyanoacetic acid structure

Cyanoacetic acid

CAS#:372-09-8

~%

2,6-Piperidinedione,4-methyl- Structure

2,6-Piperidined...

CAS#:25077-26-3

Detail
Literature: Heim Bulletin des Societes Chimiques Belges, 1931 , vol. 40, p. 216 Bulletin des Societes Chimiques Belges, 1932 , vol. 41, p. 320

 Customs

HS Code 2925190090
Summary 2925190090 other imides and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

 Synonyms

2,6-Piperidinedione,4-methyl
3-Methyl-glutarsaeureimid
3-Methylglutarimide
4-methyl-piperidine-2,6-dione
Glutarimide,3-methyl
4-Methyl-piperidin-2,6-dion
4-methylglutarimide
4-Methyl-2,6-piperidinedione
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