n-methyl-4,4'-methylenedianiline

Modify Date: 2025-08-25 17:51:17

n-methyl-4,4'-methylenedianiline Structure
n-methyl-4,4'-methylenedianiline structure
Common Name n-methyl-4,4'-methylenedianiline
CAS Number 26628-67-1 Molecular Weight 212.29000
Density 1.113g/cm3 Boiling Point 390.8ºC at 760mmHg
Molecular Formula C14H16N2 Melting Point 61-63ºC(lit.)
MSDS Chinese USA Flash Point 224.5ºC
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 4-[[4-(methylamino)phenyl]methyl]aniline
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.113g/cm3
Boiling Point 390.8ºC at 760mmHg
Melting Point 61-63ºC(lit.)
Molecular Formula C14H16N2
Molecular Weight 212.29000
Flash Point 224.5ºC
Exact Mass 212.13100
PSA 38.05000
LogP 3.55550
Vapour Pressure 2.58E-06mmHg at 25°C
Index of Refraction 1.648

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BY5700000
CHEMICAL NAME :
Aniline, N-methyl-4,4'-methylenedi-
CAS REGISTRY NUMBER :
26628-67-1
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C14-H16-N2
MOLECULAR WEIGHT :
212.32
WISWESSER LINE NOTATION :
ZR D1R DM1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Mutation in microorganisms
TEST SYSTEM :
Bacteria - Salmonella typhimurium
DOSE/DURATION :
10 ug/plate
REFERENCE :
CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 42,3475,1982

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xi: Irritant;
Risk Phrases 36/37/38
Safety Phrases 26-36
RIDADR NONH for all modes of transport
WGK Germany 3
RTECS BY5700000
HS Code 2921590090

 Synthetic Route

~67%

n-methyl-4,4'-methylenedianiline Structure

n-methyl-4,4'-m...

CAS#:26628-67-1

Literature: Katritzky, Alan R.; Lan, Xiangfu; Lam, Jamshed N. Synthesis, 1990 , p. 341 - 346

~%

n-methyl-4,4'-methylenedianiline Structure

n-methyl-4,4'-m...

CAS#:26628-67-1

Literature: Katritzky, Alan R.; Lan, Xiangfu; Lam, Jamshed N. Synthesis, 1990 , p. 341 - 346

~66%

n-methyl-4,4'-methylenedianiline Structure

n-methyl-4,4'-m...

CAS#:26628-67-1

Literature: Barluenga, Jose; Campos, Pedro J.; Roy, Miguel A.; Asensio, Gregorio Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1980 , p. 1420 - 1426

~%

Detail
Literature: Falke, P.; Tenner, R.; Knopp, H. Journal fuer Praktische Chemie (Leipzig), 1986 , vol. 328, # 1 p. 142 - 148

 Customs

HS Code 2921590090
Summary 2921590090. other aromatic polyamines and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

 Articles1

More Articles
Disposition and metabolism of the carcinogen reduced Michler's ketone in rats.

Cancer Res. 42(9) , 3475-9, (1982)

Studies on the in vivo and in vitro disposition of 4,4'-[14C]-methylenebis(N,N-dimethyl)benzamine (reduced Michler's ketone, RMK) were performed. Osborne-Mendel rats retained, after 24 hr, 78% of a p....

 Synonyms

4-((4-Aminophenyl)methyl)-N-methylbenzenamine
N-Methyl-4,4'-Methylendiamin
N-methyl-4,4'-diaminodiphenylmethane
4-(4-methylaminobenzyl)phenylamine
N-Methyl-4,4'-methylenedianiline
N-methyl-4,4'-MDA
ANILINE,N-METHYL-4,4'-METHYLENEDI
MFCD00192304
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