Methyl (trimethylsilyl)acetate

Modify Date: 2024-01-02 18:34:51

Methyl (trimethylsilyl)acetate Structure
Methyl (trimethylsilyl)acetate structure
Common Name Methyl (trimethylsilyl)acetate
CAS Number 2916-76-9 Molecular Weight 146.260
Density 0.9±0.1 g/cm3 Boiling Point 140.8±0.0 °C at 760 mmHg
Molecular Formula C6H14O2Si Melting Point N/A
MSDS Chinese USA Flash Point 32.8±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning

 Names

Name methyl 2-trimethylsilylacetate
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.9±0.1 g/cm3
Boiling Point 140.8±0.0 °C at 760 mmHg
Molecular Formula C6H14O2Si
Molecular Weight 146.260
Flash Point 32.8±0.0 °C
Exact Mass 146.076309
PSA 26.30000
LogP 1.73
Vapour Pressure 6.0±0.2 mmHg at 25°C
Index of Refraction 1.399
Storage condition Flammables area

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Warning
Hazard Statements H226-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F: Flammable;Xi: Irritant;
Risk Phrases R11
Safety Phrases 16-26-36
RIDADR UN 3272 3/PG 3
WGK Germany 3
Packaging Group II
Hazard Class 3.1
HS Code 2931900090

 Synthetic Route

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles2

More Articles
Conjugate addition of lithiotrimethylsilylacetate. A simple synthesis of methyl jasmonate via vicinal double alkylation. Nishiyama H, et al.

Tetrahedron Lett. 25(23) , 2487-88, (1984)

Z-Isomers of Steroid 17ß-Side Chain Methyl Acrylates. Pouzar V, et al.

Collect. Czech. Chem. Commun. 57(9) , 1928-36, (1992)

 Synonyms

methyl 2-(trimethylsilyl)acetate
TMSCH2CO2Me
JIHUZDFFYVRXKP-UHFFFAOYSA
Acetic acid, 2-(trimethylsilyl)-, methyl ester
EINECS 220-845-0
MFCD00008450
(Me)3SiCH2CO2Me
Methyl (trimethylsilyl)acetate
methy C-(trimethylsilyl)acetate
Methyl(trimethylsilyl)acetate
Me3SiCH2CO2CH3
(carbomethoxymethyl)trimethylsilane