P-TOLYL TRIFLATE
P-TOLYL TRIFLATE structure
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Common Name | P-TOLYL TRIFLATE | ||
|---|---|---|---|---|
| CAS Number | 29540-83-8 | Molecular Weight | 240.20000 | |
| Density | 1.342 g/mL at 25ºC(lit.) | Boiling Point | 115ºC50 mm Hg(lit.) | |
| Molecular Formula | C8H7F3O3S | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 192 °F | |
| Symbol |
GHS05, GHS06, GHS08 |
Signal Word | Danger | |
| Name | (4-methylphenyl) trifluoromethanesulfonate |
|---|---|
| Synonym | More Synonyms |
| Density | 1.342 g/mL at 25ºC(lit.) |
|---|---|
| Boiling Point | 115ºC50 mm Hg(lit.) |
| Molecular Formula | C8H7F3O3S |
| Molecular Weight | 240.20000 |
| Flash Point | 192 °F |
| Exact Mass | 240.00700 |
| PSA | 51.75000 |
| LogP | 3.30420 |
| Vapour Pressure | 0.0242mmHg at 25°C |
| Index of Refraction | n20/D 1.441(lit.) |
| Symbol |
GHS05, GHS06, GHS08 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H301-H311-H314-H331-H351 |
| Precautionary Statements | P261-P280-P301 + P310-P305 + P351 + P338-P310 |
| Personal Protective Equipment | Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter |
| Hazard Codes | T: Toxic; |
| Risk Phrases | 23/24/25-34-40 |
| Safety Phrases | 16-26-36/37/39-45 |
| RIDADR | UN 3265 8/PG 2 |
| HS Code | 2904909090 |
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~95%
P-TOLYL TRIFLATE CAS#:29540-83-8 |
| Literature: Goossen, Lukas J.; Linder, Christophe; Rodriguez, Nuria; Lange, Paul P. Chemistry - A European Journal, 2009 , vol. 15, # 37 p. 9336 - 9349 Title/Abstract Full Text View citing articles Show Details Goossen, Lukas J.; Lange, Paul P.; Rodriguez, Nuria; Linder, Christophe Chemistry - A European Journal, 2010 , vol. 16, # 13 p. 3906 - 3909 |
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~88%
P-TOLYL TRIFLATE CAS#:29540-83-8 |
| Literature: University of Maryland Patent: US6414173 B1, 2002 ; |
|
~43%
P-TOLYL TRIFLATE CAS#:29540-83-8 |
| Literature: Picherit; Wagner; Uguen Tetrahedron Letters, 2004 , vol. 45, # 12 p. 2579 - 2583 |
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~77%
P-TOLYL TRIFLATE CAS#:29540-83-8 |
| Literature: Yoneda, Norihiko; Fukuhara, Tsuyoshi; Mizokami, Takao; Suzuki, Akira Chemistry Letters, 1991 , # 3 p. 459 - 460 |
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~74%
P-TOLYL TRIFLATE CAS#:29540-83-8 |
| Literature: Effenberger; Mack Tetrahedron Letters, 1970 , p. 3947 |
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~6%
P-TOLYL TRIFLATE CAS#:29540-83-8
Detail
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| Literature: Journal of Fluorine Chemistry, , vol. 107, # 2 p. 321 - 327 |
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~%
P-TOLYL TRIFLATE CAS#:29540-83-8 |
| Literature: Tetrahedron Letters, , vol. 45, # 12 p. 2579 - 2583 |
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~%
P-TOLYL TRIFLATE CAS#:29540-83-8 |
| Literature: Chemistry Letters, , # 3 p. 459 - 460 |
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~%
P-TOLYL TRIFLATE CAS#:29540-83-8
Detail
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| Literature: Zhurnal Organicheskoi Khimii, , vol. 12, p. 686 Zhurnal Organicheskoi Khimii, , vol. 12, p. 690 C.A., , vol. 84, p. 164331 F: PerFHalOrg.SVol.3, 6.2.3.1, page 48 - 120 |
![1H-Imidazole,1-[(trifluoromethyl)sulfonyl]- structure](https://image.chemsrc.com/caspic/277/29540-81-6.png)
| Precursor 9 | |
|---|---|
| DownStream 10 | |
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CAS#:380481-66-3| HS Code | 2904909090 |
|---|---|
| Summary | HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0% |
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Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel.
J. Am. Chem. Soc. 130(1) , 195-200, (2008) The asymmetric alpha-arylation of ketones with aryl triflates is described, and the use of this electrophile with nickel and palladium catalysts containing a segphos derivative increases substantially... |
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Direct arylation of azine N-oxides with aryl triflates. Schipper DJ, et al.
Tetrahedron 65(26) , 4977-4983, (2009)
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| para-tolyl triflate |
| 4-methylphenyl triflate |
| p-Tolyl trifluoromethanesulfonate |
| 4-tolyltriflate |
| p-trifluoromethanesulfonyloxytoluene |
| MFCD00192507 |
| 4-Tolyl trifluoromethanesulfonate |
| p-Tolyl Triflate |
| ghl.PD_Mitscher_leg0.1333 |
| trifluoromethanesulfonic acid p-tolyl ester |
| 4-Methylphenyl trifluoromethanesulfonate |