TRIMETHYLSILYLMETHYL ISOCYANIDE

Modify Date: 2024-01-09 21:51:32

TRIMETHYLSILYLMETHYL ISOCYANIDE Structure
TRIMETHYLSILYLMETHYL ISOCYANIDE structure
Common Name TRIMETHYLSILYLMETHYL ISOCYANIDE
CAS Number 30718-17-3 Molecular Weight 113.23300
Density 0.803 g/mL at 25ºC(lit.) Boiling Point 52-53ºC35 mm Hg(lit.)
Molecular Formula C5H11NSi Melting Point N/A
MSDS Chinese USA Flash Point 82 °F
Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger

 Names

Name isocyanomethyl(trimethyl)silane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.803 g/mL at 25ºC(lit.)
Boiling Point 52-53ºC35 mm Hg(lit.)
Molecular Formula C5H11NSi
Molecular Weight 113.23300
Flash Point 82 °F
Exact Mass 113.06600
LogP 1.43210
Index of Refraction n20/D 1.416(lit.)

 Safety Information

Symbol GHS02 GHS06
GHS02, GHS06
Signal Word Danger
Hazard Statements H225-H301-H311-H331
Precautionary Statements P210-P261-P280-P301 + P310-P311
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F,T
Risk Phrases R11;R23/24/25
Safety Phrases S16;S45;S36/S37/S39
RIDADR UN 1993 3/PG 3
Packaging Group III
Hazard Class 3.2
HS Code 2931900090

 Synthetic Route

~%

TRIMETHYLSILYLMETHYL ISOCYANIDE Structure

TRIMETHYLSILYLM...

CAS#:30718-17-3

Literature: Smith, Richard; Livinghouse, Tom Synthetic Communications, 1984 , vol. 14, # 7 p. 639 - 646

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles4

More Articles
An improved synthesis of trimethylsilylmethyl isocyanide and some of its reactions with nucleophiles. Smith R and Livinghouse T.

Synth. Commun. 14(7) , 639-646., (1984)

An Improved Synthesis of Trimethylsilylmethyl Isocyanide. Brouwer AC and Van Leusen AM.

Synth. Commun. 16(8) , 865-869., (1986)

A (η1-iminoacyl) zirconocene complex formed by alkyl isocyanide insertion into the metal-to-carbon bond of (η2-formaldehyde) zirconocene. Erker G, et al.

Organometallics 10(4) , 1201-3, (1991)

 Synonyms

MFCD00043056
trimethylsilyl isocyanide
TRIMETHYLSILYLMETHYL ISOCYANIDE