Tsar

Modify Date: 2024-01-09 13:14:26

Tsar Structure
Tsar structure
 Common Name Tsar
CAS Number 31218-83-4 Molecular Weight 281.31
Density 1.2±0.1 g/cm3 Boiling Point 321.1±44.0 °C at 760 mmHg
Molecular Formula C10H20NO4PS Melting Point <25℃
MSDS Chinese USA Flash Point 148.0±28.4 °C
Symbol GHS06 GHS09
GHS06, GHS09		 Signal Word Danger

 Use of Tsar


Propetamphos is an organophosphorus insecticide. Propetamphos causes cytotoxicity and oxidative stress[1][2].

 Names

Name propetamphos
Synonym More Synonyms

 Tsar Biological Activity

Description Propetamphos is an organophosphorus insecticide. Propetamphos causes cytotoxicity and oxidative stress[1][2].
Related Catalog
In Vivo Propolis (100 mg/kg/天；口服；28 天) 对由 Propetamphos 诱导的 Wistar Albino 大鼠表现出抗自由基和抗氧化作用[1]。
References

[1]. Kanbur M, et al. Antioxidant effect of propolis against exposure to propetamphos in rats. Ecotoxicol Environ Saf. 2009 Mar;72(3):909-15.  

[2]. Cetin E, et al. Propetamphos-induced changes in haematological and biochemical parameters of female rats: protective role of propolis. Food Chem Toxicol. 2010 Jul;48(7):1806-10.  

 Chemical & Physical Properties

Density 1.2±0.1 g/cm3
Boiling Point 321.1±44.0 °C at 760 mmHg
Melting Point <25℃
Molecular Formula C10H20NO4PS
Molecular Weight 281.31
Flash Point 148.0±28.4 °C
Exact Mass 281.085052
PSA 98.69000
LogP 1.61
Vapour Pressure 0.0±0.7 mmHg at 25°C
Index of Refraction 1.495
Storage condition APPROX 4°C

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GQ4750000
CHEMICAL NAME :
Crotonic acid, 3-hydroxy-, isopropyl ester, O-ester with O-methyl ethylphosphoramidothioate, (E)-
CAS REGISTRY NUMBER :
31218-83-4
LAST UPDATED :
199706
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C10-H20-N-O4-P-S
MOLECULAR WEIGHT :
281.34

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
62400 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 37,1621,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
564 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YKYUA6 Yakkyoku. Pharmacy. (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo, Japan) V.1- 1950- Volume(issue)/page/year: 35,1315,1984
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
49 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JAFCAU Journal of Agricultural and Food Chemistry. (American Chemical Soc., Distribution Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037) V.1- 1953- Volume(issue)/page/year: 34,79,1986
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
130 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PSTDAN Pesticides. (Colour Pub. Pvt. Ltd., 126-A Dhuruwadi, Off Dr. Nariman Rd., Bombay 400-025, India) V.1- 1967- Volume(issue)/page/year: 15(10),37,1981
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
4 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PSTDAN Pesticides. (Colour Pub. Pvt. Ltd., 126-A Dhuruwadi, Off Dr. Nariman Rd., Bombay 400-025, India) V.1- 1967- Volume(issue)/page/year: 15(10),37,1981 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2243 No. of Facilities: 6 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 6 (estimated)

 Safety Information

Symbol GHS06 GHS09
GHS06, GHS09
Signal Word Danger
Hazard Statements H301 + H311-H330-H410
Precautionary Statements P260-P273-P280-P284-P301 + P310 + P330-P304 + P340 + P310
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes T: Toxic;N: Dangerous for the environment;
Risk Phrases R25
Safety Phrases S37;S45;S60;S61
RIDADR UN 3018
RTECS GQ4750000
Packaging Group II
Hazard Class 6.1(b)
HS Code 2931900090

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles25

More Articles
Activated transformations of organophosphorus insecticides in the case of non-AChE inhibitory oxons.

Pest Manag. Sci. 58(11) , 1107-17, (2002)

Many organophosphorus (OP) compounds are of the thiono form and in insects or animals are converted by microsomal mixed function oxidases (MFO) into the oxon forms which inhibit acetylcholinesterase (...

Insecticide susceptibility of cat flea (Siphonaptera: Pulicidae) pupae.

J. Econ. Entomol. 89(2) , 421-7, (1996)

Studies were conducted to investigate what protective nature the cocoon and nylon carpeting has against the performance of insecticides directed at cat flea, Ctenocephalides felis (Bouché), pupae deve...

Survey of levels of propetamphos and diazinon used to control sheep scab in Northern Ireland.

Vet. Rec. 126(11) , 263-5, (1990)

As a result of an increase in the incidence of sheep scab in Northern Ireland, the concentrations of propetamphos and diazinon were measured during 1987 and 1988 in fleece and liquid dip samples from ...

 Synonyms

1-methylethyl (2E)-3-[[(ethylamino)methoxyphosphinothioyl]oxy]-2-butenoate
Propetamphos [BAN]
PROPETAMPHOS
Safrotin S 200
Deadmag
(E)-3-Hydroxycrotonic Acid Isopropyl Ester O-Ester with o-Methyl Ethylphosphoramidothioate
2-Butenoic acid, 3-[[(ethylamino)methoxyphosphinothioyl]oxy]-, 1-methylethyl ester, (2E)-
Seraphos
propan-2-yl (2E)-3-{[(ethylamino)(methoxy)phosphorothioyl]oxy}but-2-enoate
Isopropyl-(2E)-3-{[(ethylamino)(methoxy)phosphorothioyl]oxy}but-2-enoat
propan-2-yl (E)-3-[ethylamino(methoxy)phosphinothioyl]oxybut-2-enoate
EINECS 250-517-2
1-methylethyl (2E)-3-{[(ethylamino)(methoxy)phosphorothioyl]oxy}but-2-enoate
Isopropyl 3-(ethylamino(methoxy)phosphinothioyloxy)isocrotonate
PS1076_SUPELCO
propan-2-yl (2E)-3-{[(Ξ)-N-ethyl-P-methoxyphosphoramidothioyl]oxy}but-2-enoate
Blotic
(E)-1-Methylethyl 3-[[(Ethylamino)methoxyphosphinothioyl]oxy]-2-butenoate
(E)-O-2-Isopropoxycarbonyl-1-methylvinyl O-Methyl Ethylphosphoramidothioate
MFCD00137384
Isopropyl (2E)-3-{[(ethylamino)(methoxy)phosphorothioyl]oxy}but-2-enoate
Tsar
2-Butenoic acid, 3-(((ethylamino)methoxyphosphinothioyl)oxy)-, 1-methylethyl ester, (E)-
Isopropyl (2E)-3-{[(ethylamino)(methoxy)phosphorothioyl]oxy}-2-butenoate
SAN 322I
(RS)-[(E)-O-2-isopropoxycarbonyl-1-methylvinyl O-methyl ethylphosphoramidothioate]
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