Bis(dibenzylideneacetone)palladium structure
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Common Name | Bis(dibenzylideneacetone)palladium | ||
|---|---|---|---|---|
| CAS Number | 32005-36-0 | Molecular Weight | 613.14 | |
| Density | N/A | Boiling Point | 400.7ºC at 760 mmHg | |
| Molecular Formula | C36H42O2Pd | Melting Point | 150°C | |
| MSDS | Chinese USA | Flash Point | 176.1ºC | |
Use of Bis(dibenzylideneacetone)palladiumBis(dibenzylideneacetone)palladium is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
| Name | (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one,palladium |
|---|---|
| Synonym | More Synonyms |
| Description | Bis(dibenzylideneacetone)palladium is a biochemical reagent that can be used as a biological material or organic compound for life science related research. |
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| Related Catalog | |
| In Vitro | 氢化、异构化、羰基化、氧化、CC键形成。Bis(dibenzylideneacetone)palladium(0) 用作制备烯丙基取代的环戊二烯的试剂。它作为均相催化剂以及各种亲核试剂对乙酸烯丙酯的烷基化作用。此外,它还用于铃木反应。 |
| Boiling Point | 400.7ºC at 760 mmHg |
|---|---|
| Melting Point | 150°C |
| Molecular Formula | C36H42O2Pd |
| Molecular Weight | 613.14 |
| Flash Point | 176.1ºC |
| Exact Mass | 574.112427 |
| PSA | 34.14000 |
| LogP | 7.96460 |
| InChIKey | UKSZBOKPHAQOMP-UHFFFAOYSA-N |
| SMILES | O=C(C=Cc1ccccc1)C=Cc1ccccc1.O=C(C=Cc1ccccc1)C=Cc1ccccc1.[Pd] |
| Water Solubility | insoluble |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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| Hazard Codes | Xi:Irritant |
| Risk Phrases | R36/38 |
| Safety Phrases | S22-S24/25-S37/39-S26 |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3 |
| HS Code | 2914399090 |
| Precursor 0 | |
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| DownStream 9 | |
| HS Code | 2914399090 |
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| Summary | 2914399090. other aromatic ketones without other oxygen function. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0% |
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Palladium-catalyzed, asymmetric Mizoroki-Heck reaction of benzylic electrophiles using phosphoramidites as chiral ligands.
J. Am. Chem. Soc. 134(29) , 11833-5, (2012) We report herein the first examples of asymmetric Mizoroki-Heck reactions using benzyl electrophiles. A new phosphoramidite was identified to be an effective chiral ligand in the palladium-catalyzed r... |
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Controlling olefin isomerization in the heck reaction with neopentyl phosphine ligands.
J. Org. Chem. , (2014) The use of neopentyl phosphine ligands was examined in the coupling of aryl bromides with alkenes. Di-tert-butylneopentylphosphine (DTBNpP) was found to promote Heck couplings with aryl bromides at am... |
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Sterically bulky thioureas as air- and moisture-stable ligands for pd-catalyzed Heck reactions of aryl halides.
Org. Lett. 6 , 1577, (2004) We demonstrate that sterically bulky N,N'-disubstituted cyclic thiourea-Pd(0) complexes are air- and moisture-stable and highly active catalysts for palladium-catalyzed Heck reaction of aryl iodides a... |
| (1E,4E)-1,5-diphenylpenta-1,4-dien-3-one |
| 1,4-Pentadien-3-one, 1,5-diphenyl-, (1E,4E)-, palladium salt (2:1) |
| Bis(dibenzylideneacetone) palladium(0) |
| (1E,4E)-1,5-Diphenyl-1,4-pentadien-3-one - palladium (2:1) |
| Bis(dibenzylideneacetone)palladium(0) |
| bis-(dibenzylideneacetone)palladium(0) |
| Palladium(0) bis(dibenzylideneacetone) |
| (1E,4E)-1,5-Diphenylpenta-1,4-dien-3-one - palladium (2:1) |
| PD(DBA)2 |
| palladium bis(dibenzylideneacetone) |
| Bis(dibenzylideneacetone)palladium |
| MFCD00051942 |