Nickel(2+) acetylacetonate

Modify Date: 2024-01-02 20:01:47

Nickel(2+) acetylacetonate Structure
Nickel(2+) acetylacetonate structure
 Common Name Nickel(2+) acetylacetonate
CAS Number 3264-82-2 Molecular Weight 256.909
Density 0,145 g/cm3 Boiling Point 220 °C (11 mmHg)
Molecular Formula C10H14NiO4 Melting Point 230 °C (dec.)(lit.)
MSDS Chinese USA Flash Point >200°C
Symbol GHS07 GHS08
GHS07, GHS08		 Signal Word Danger

 Names

Name Bis(2,4-pentanediono)nickel
Synonym More Synonyms

 Chemical & Physical Properties

Density 0,145 g/cm3
Boiling Point 220 °C (11 mmHg)
Melting Point 230 °C (dec.)(lit.)
Molecular Formula C10H14NiO4
Molecular Weight 256.909
Flash Point >200°C
Exact Mass 256.024567
PSA 52.60000
LogP 1.92020
Index of Refraction 1.57-1.64

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SA2100000
CHEMICAL NAME :
2,4-Pentanedione, nickel(II) deriv.
CAS REGISTRY NUMBER :
3264-82-2
LAST UPDATED :
199712
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C10-H14-Ni-O4
MOLECULAR WEIGHT :
256.95
WISWESSER LINE NOTATION :
1V1V1 &-NI-

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
125 mg/kg
REFERENCE :
CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 4,231,1952 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5635 No. of Facilities: 274 (estimated) No. of Industries: 2 No. of Occupations: 7 No. of Employees: 3418 (estimated) No. of Female Employees: 1678 (estimated)

 Safety Information

Symbol GHS07 GHS08
GHS07, GHS08
Signal Word Danger
Hazard Statements H302-H317-H350
Precautionary Statements P201-P280-P301 + P312 + P330-P308 + P313
Personal Protective Equipment Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges
Hazard Codes Xn:Harmful;
Risk Phrases R22;R40;R43
Safety Phrases 53-36/37/39-45-36/37
RIDADR NONH for all modes of transport
WGK Germany 3
RTECS SA2100000
HS Code 29420000

 Synthetic Route

Nickel-acetic acid (1:1) structure

Nickel-acetic a...

CAS#:373-02-4

2,4-Pentandione structure

2,4-Pentandione

CAS#:123-54-6

~%

Nickel(2+) acetylacetonate Structure

Nickel(2+) acet...

CAS#:3264-82-2

Literature: Thermochimica Acta, , vol. 178, p. 241 - 248
trans-[Ni(acetylacetonato)2(PMe2Ph)2] structure

trans-[Ni(acety...

CAS#:1236196-28-3

~%

Nickel(2+) acetylacetonate Structure

Nickel(2+) acet...

CAS#:3264-82-2

dimethylphenylphosphine structure

dimethylphenylp...

CAS#:672-66-2

Literature: Organometallics, , vol. 29, # 21 p. 5098 - 5102
nickel methanolate structure

nickel methanolate

CAS#:7245-23-0

4-hydroxypent-3-en-2-one structure

4-hydroxypent-3...

CAS#:26567-75-9

~%

Nickel(2+) acetylacetonate Structure

Nickel(2+) acet...

CAS#:3264-82-2

Literature: Journal of the Indian Chemical Society, , vol. 59, # 6 p. 715 - 722

 Customs

HS Code 2918300090
Summary 2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Articles4

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Ni-assisted thermal chemical vapor deposition (TCVD) is one of the most common techniques for the growth of carbon nanofibres/nanotubes (CNFs/CNTs). However, some fundamental issues related to the cat...

 Synonyms

Nickel(II) Acetylacetonate
anhydrous nickel acetylacetonate
3-Penten-2-one, 4-hydroxy-, nickel(2+) salt, (3Z)- (2:1)
Acetylacetonenickel
Nickel bis(acetylacetonate)
2,4-Pentanedione nickel(II) derivative
NICKEL PENTANEDIONATE
NICKEL ACETYLACETONATE
EINECS 221-875-7
Nickel(2+) bis[(2Z)-4-oxo-2-penten-2-olate]
MFCD00000024
Acetylacetonate nickel
Nickel(2+) bis[(2Z)-4-oxopent-2-en-2-olate]
Bis(acetylacetonato)nickel(II)
Nickel(2+) acetylacetonate
Acetylacetonato nickel
Bis(2,4-pentanedionato)nickel(II)
Nickel acetonylacetonate
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