Methyl 3-bromopropanoate

Modify Date: 2025-08-25 13:03:22

Methyl 3-bromopropanoate structure	Common Name	Methyl 3-bromopropanoate
	CAS Number	3395-91-3	Molecular Weight	167.001
	Density	1.5±0.1 g/cm3	Boiling Point	166.5±0.0 °C at 760 mmHg
	Molecular Formula	C₄H₇BrO₂	Melting Point	75°C
	MSDS	Chinese USA	Flash Point	75.0±0.0 °C
	Symbol	GHS07	Signal Word	Warning

Name	methyl 3-bromopropanoate
Synonym	More Synonyms

Density	1.5±0.1 g/cm3
Boiling Point	166.5±0.0 °C at 760 mmHg
Melting Point	75°C
Molecular Formula	C₄H₇BrO₂
Molecular Weight	167.001
Flash Point	75.0±0.0 °C
Exact Mass	165.962936
PSA	26.30000
LogP	1.15
Vapour Pressure	1.8±0.3 mmHg at 25°C
Index of Refraction	1.453
Storage condition	Store at R.T.
Water Solubility	Immiscible

Methyl 3-bromopropanoate MSDS(Chinese)

CHEMICAL IDENTIFICATION

RTECS NUMBER :: UA2451790

CHEMICAL NAME :: Propanoic acid, 3-bromo-, methyl ester

CAS REGISTRY NUMBER :: 3395-91-3

LAST UPDATED :: 199710

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C4-H7-Br-O2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1600 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - ataxia Vascular - regional or general arteriolar or venous dilation

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0570991

Symbol	GHS07
Signal Word	Warning
Hazard Statements	H302-H315-H319-H335
Precautionary Statements	P261-P305 + P351 + P338
Personal Protective Equipment	Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes	Xn:Harmful;
Risk Phrases	R22;R36/37/38
Safety Phrases	S26-S37/39
WGK Germany	3
RTECS	UA2451790
Packaging Group	I; II; III
Hazard Class	6.1
HS Code	29159080

Methyl propanoate

CAS#:554-12-1

~87%

Methyl 3-bromop...

CAS#:3395-91-3

Literature: PHARMACIA and UPJOHN COMPANY Patent: WO2004/13137 A1, 2004 ; Location in patent: Page 76 ; WO 2004/013137 A1

acrylic acid me...

CAS#:292638-85-8

~97%

Methyl 3-bromop...

CAS#:3395-91-3

Literature: Lee, Adam Shih-Yuan; Wang, Shu-Huei; Chang, Yu-Ting Journal of the Chinese Chemical Society, 2014 , vol. 61, # 3 p. 364 - 368

3-Bromopropanoi...

CAS#:590-92-1

Methanol

CAS#:67-56-1

~82%

Methyl 3-bromop...

CAS#:3395-91-3

Literature: Dawadi, Prativa B. S.; Schulten, Els A. M.; Lugtenburg, Johan Journal of Labelled Compounds and Radiopharmaceuticals, 2009 , vol. 52, # 9 p. 341 - 349

Methanol

CAS#:67-56-1

~69%

Methyl 3-bromop...

CAS#:3395-91-3

Methyl 3-methox...

CAS#:3852-09-3

1,2-Dibromoethane

CAS#:106-93-4

Detail

Literature: Schmidt, E. K. G.; Wiese, W. Tetrahedron Letters, 1980 , vol. 21, p. 4425 - 4428

Methanol

CAS#:67-56-1

β-Propiolactone

CAS#:57-57-8

~56%

Methyl 3-bromop...

CAS#:3395-91-3

Literature: Wolfe, Saul; Wilson, Marie-Claire; Cheng, Ming-Huei; Shustov, Gennady V.; Akuche, Christiana I. Canadian Journal of Chemistry, 2003 , vol. 81, # 8 p. 937 - 960

N/A

CAS#:14213-56-0

Methyl 3-bromop...

CAS#:3395-91-3

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. 34, p. 262 - 271

4-Methoxy-4-oxo...

CAS#:3878-55-5

Methyl 3-bromop...

CAS#:3395-91-3

Literature: Journal of Organic Chemistry, , vol. 34, # 4 p. 1172 - 1173

alpha-Bromostyrene

CAS#:98-81-7

Acrylic acid

CAS#:79-10-7

Methyl 3-bromop...

CAS#:3395-91-3

(+/-)-1,2-dihyd...

CAS#:16827-42-2

Literature: Chemische Berichte, , vol. 87, p. 237,244

Precursor 8
CAS#:554-12-1 Methyl propanoate CAS#:292638-85-8 acrylic acid me... CAS#:590-92-1 3-Bromopropanoi... CAS#:67-56-1 Methanol
CAS#:57-57-8 β-Propiolactone CAS#:3878-55-5 4-Methoxy-4-oxo... CAS#:98-81-7 alpha-Bromostyrene CAS#:79-10-7 Acrylic acid
DownStream 10
CAS#:3699-67-0 Ethyl 3-(dietho... CAS#:53733-94-1 Methyl 3-[(3-me... CAS#:35979-69-2 4-Bromo-2-methy... CAS#:5439-14-5 3,4-Dihydro-2H-...
CAS#:14290-81-4 (3-methoxy-3-ox... CAS#:20497-95-4 METHYL 3-NITROP... CAS#:22623-71-8 2-Thioxo-3-thia... CAS#:20948-40-7 methyl 3-(2-for...
CAS#:103-25-3 Methyl 3-phenyl... CAS#:1112-48-7 Bromo(triethyl)...

HS Code	2915900090
Summary	2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%

Samarium diiodide promoted spirolactonization of cycloalkanones. Hua Z, et al.

Tetrahedron 47(34) , 7037-7044, (1991)

Methyl 3-Bromopropionate

Methyl 3-bromopropanoate

Propionic acid, 3-bromo-, methyl ester (8CI)

Propanoic acid, 3-bromo-, methyl ester

Propanoic acid,3-bromo-,methyl ester

MFCD00000250

EINECS 222-247-5

Propionic acid,3-bromo-,methyl ester

Methyl β-bromopropionate

3-Bromopropanoic acid methyl ester

3-Bromopropionic Acid Methyl Ester

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Shanghai Nianxing Industrial Co., Ltd
China
Product Name: Methyl 3-bromopropanoate
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China
Product Name: Methyl 3-bromopropanoate
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Dayang Chem (Hangzhou) Co., Ltd.
China
Product Name: Methyl 3-bromopropionate
Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
Purity: 98.0%
Delivery: Inquiry
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Zhongshan Xingrui Chemical Co. , Ltd.
China
Product Name: Methyl 3-bromopropanoate
Price: ￥Inquiry/1kg ￥Inquiry/25kg ￥Inquiry/200kg
Purity: 99.0%
Delivery: 3 Day
Contact: Wang Jie
Email: 3096638339@qq.com

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Methyl 3-bromopropanoate

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