2,6-Dibromo-4-fluorophenol

Modify Date: 2024-01-09 17:43:41

2,6-Dibromo-4-fluorophenol Structure
2,6-Dibromo-4-fluorophenol structure
Common Name 2,6-Dibromo-4-fluorophenol
CAS Number 344-20-7 Molecular Weight 269.894
Density 2.2±0.1 g/cm3 Boiling Point 219.5±35.0 °C at 760 mmHg
Molecular Formula C6H3Br2FO Melting Point 55-57°C
MSDS Chinese USA Flash Point 86.5±25.9 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name 2,6-dibromo-4-fluorophenol
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.2±0.1 g/cm3
Boiling Point 219.5±35.0 °C at 760 mmHg
Melting Point 55-57°C
Molecular Formula C6H3Br2FO
Molecular Weight 269.894
Flash Point 86.5±25.9 °C
Exact Mass 267.853455
PSA 20.23000
LogP 3.68
Vapour Pressure 0.1±0.4 mmHg at 25°C
Index of Refraction 1.616
Storage condition 2~8℃

 MSDS

2,6-Dibromo-4-fluorophenol Revision number: 5
SAFETY DATA SHEET

Section1. IDENTIFICATION
Product name:2,6-Dibromo-4-fluorophenol

Revision number:5

Section2. HAZARDS IDENTIFICATION
GHS classification
PHYSICAL HAZARDSNot classified
HEALTH HAZARDS
Acute toxicity (Oral)Category 4
Category 4
Acute toxicity (Dermal)
Acute toxicity (Inhalation)Category 4
Category 2
Skin corrosion/irritation
Serious eye damage/eye irritationCategory 2A
Not classified
ENVIRONMENTAL HAZARDS
GHS label elements, including precautionary statements
Pictograms or hazard symbols
Signal wordWarning
Harmful if swallowed, in contact with skin or if inhaled
Hazard statements
Causes skin irritation
Causes serious eye irritation
Precautionary statements:
Avoid breathing dust/fume/gas/mist/vapours/spray.
[Prevention]
Use only outdoors or in a well-ventilated area.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly after handling.
Wear protective gloves and eye/face protection.
[Response]IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
Rinse mouth.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention.
IF ON SKIN: Gently wash with plenty of soap and water.
If skin irritation occurs: Get medical advice/attention.
Wash contaminated clothing before reuse.
Call a POISON CENTER or doctor/physician if you feel unwell.
2,6-Dibromo-4-fluorophenol

Section2. HAZARDS IDENTIFICATION
[Disposal]Dispose of contents/container through a waste management company authorized by
the local government.

Section3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance/mixture:Substance
Components:2,6-Dibromo-4-fluorophenol
>98.0%(GC)(T)
Percent:
CAS Number:344-20-7
Chemical Formula:C6H3Br2FO

Section4. FIRST AID MEASURES
Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Skin contact:Remove/Take off immediately all contaminated clothing. Gently wash with plenty of
soap and water. If skin irritation or rash occurs: Get medical advice/attention.
Rinse cautiously with water for several minutes. Remove contact lenses, if present
Eye contact:
and easy to do. Continue rinsing. If eye irritation persists: Get medical
advice/attention.
Ingestion:Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth.
Protection of first-aiders:A rescuer should wear personal protective equipment, such as rubber gloves and air-
tight goggles.

Section5. FIRE-FIGHTING MEASURES
Suitable extinguishingDry chemical, foam, water spray, carbon dioxide.
media:
Specific hazards arising Take care as it may decompose upon combustion or in high temperatures to
generate poisonous fume.
from the chemical:
Precautions for firefighters: Fire-extinguishing work is done from the windward and the suitable fire-extinguishing
method according to the surrounding situation is used. Uninvolved persons should
evacuate to a safe place. In case of fire in the surroundings: Remove movable
containers if safe to do so.
Special protectiveWhen extinguishing fire, be sure to wear personal protective equipment.
equipment for firefighters:

Section6. ACCIDENTAL RELEASE MEASURES
Personal precautions,Use personal protective equipment. Keep people away from and upwind of spill/leak.
protective equipment and Entry to non-involved personnel should be controlled around the leakage area by
emergency procedures: roping off, etc.
Environmental precautions: Prevent product from entering drains.
Methods and materials for Sweep dust to collect it into an airtight container, taking care not to disperse it.
containment and cleaning Adhered or collected material should be promptly disposed of, in accordance with
up: appropriate laws and regulations.

Section7. HANDLING AND STORAGE
Precautions for safe handling
Handling is performed in a well ventilated place. Wear suitable protective equipment.
Technical measures:
Prevent dispersion of dust. Wash hands and face thoroughly after handling.
Use a local exhaust if dust or aerosol will be generated.
Advice on safe handling: Avoid contact with skin, eyes and clothing.
Conditions for safe storage, including any
incompatibilities
Keep container tightly closed. Store in a cool and dark place.
Storage conditions:
Store under inert gas.
Store away from incompatible materials such as oxidizing agents.
Air-sensitive
Comply with laws.
Packaging material:
2,6-Dibromo-4-fluorophenol

Section8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls:Install a closed system or local exhaust as possible so that workers should not be
exposed directly. Also install safety shower and eye bath.
Personal protective equipment
Respiratory protection: Dust respirator. Follow local and national regulations.
Protective gloves.
Hand protection:
Eye protection:Safety glasses. A face-shield, if the situation requires.
Skin and body protection: Protective clothing. Protective boots, if the situation requires.

Section9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state (20°C):Solid
Form:Crystal- Powder
Very pale yellow - Yellow
Colour:
Odour:No data available
pH: No data available
Melting point/freezing point:56°C
Boiling point/range:No data available
Flash point:No data available
Flammability or explosive
limits:
Lower:No data available
Upper:No data available
Relative density:No data available
Solubility(ies):
No data available
[Water]
[Other solvents]
Soluble:Methanol

Section10. STABILITY AND REACTIVITY
Chemical stability:Stable under proper conditions.
Possibility of hazardous No special reactivity has been reported.
reactions:
Incompatible materials: Oxidizing agents
Hazardous decomposition Carbon monoxide, Carbon dioxide, Hydrogen fluoride, Hydrogen bromide
products:

Section11. TOXICOLOGICAL INFORMATION
Acute Toxicity:No data available
Skin corrosion/irritation: No data available
Serious eyeNo data available
damage/irritation:
Germ cell mutagenicity: No data available
Carcinogenicity:
No data available
IARC =
NTP =No data available
Reproductive toxicity:No data available

Section12. ECOLOGICAL INFORMATION
Ecotoxicity:
Fish:No data available
Crustacea:No data available
Algae:No data available
Persistence / degradability: No data available
BioaccumulativeNo data available
potential(BCF):
Mobility in soil
2,6-Dibromo-4-fluorophenol

Section12. ECOLOGICAL INFORMATION
Log Pow:No data available
Soil adsorption (Koc): No data available
Henry's LawNo data available
constant(PaM3/mol):

Section13. DISPOSAL CONSIDERATIONS
Recycle to process, if possible. Consult your local regional authorities. You may be able to dissolve or mix material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system.
Observe all federal, state and local regulations when disposing of the substance.

Section14. TRANSPORT INFORMATION
Hazards Class:Does not correspond to the classification standard of the United Nations
UN-No:Not listed

Section15. REGULATORY INFORMATION
Safe management ordinance of dangerous chemical product (State Council announces on January 26, 2002
and revised on February 16,2011): Safe use and production, the storage of a dangerous chemical, transport,
loading and unloading were prescribed.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302 + H312 + H332-H315-H319-H335
Precautionary Statements P261-P280-P305 + P351 + P338
Personal Protective Equipment dust mask type N95 (US);Eyeshields;Gloves
Hazard Codes Xn:Harmful;
Risk Phrases R20/21/22;R36/37/38
Safety Phrases S22-S36/37-S36-S26
RIDADR NONH for all modes of transport
HS Code 2908199090

 Synthetic Route

~90%

2,6-Dibromo-4-fluorophenol Structure

2,6-Dibromo-4-f...

CAS#:344-20-7

Literature: GALENEA CORPORATION; ELDER, Amy; HARRIMAN, Geraldine; LEIT, Silvana; LI, Jie; SARD, Howard; ZHANG, Yiliang; WILSON, Doug Patent: WO2011/19738 A1, 2011 ; Location in patent: Page/Page column 143 ; WO 2011/019738 A1

~%

2,6-Dibromo-4-fluorophenol Structure

2,6-Dibromo-4-f...

CAS#:344-20-7

Literature: Journal of the American Chemical Society, , vol. 81, p. 94,95, 97

~%

2,6-Dibromo-4-fluorophenol Structure

2,6-Dibromo-4-f...

CAS#:344-20-7

Literature: Canadian Journal of Chemistry, , vol. 62, p. 1592 - 1597

~%

2,6-Dibromo-4-fluorophenol Structure

2,6-Dibromo-4-f...

CAS#:344-20-7

Literature: Journal of the American Chemical Society, , vol. 66, p. 2080

~%

2,6-Dibromo-4-fluorophenol Structure

2,6-Dibromo-4-f...

CAS#:344-20-7

Literature: Journal of the Chemical Society, , p. 1085

 Customs

HS Code 2908199090
Summary HS: 2908199090. derivatives of polyphenols or phenol-alcohols containing only halogen substituents and their salts. VAT:17.0%. tax rebate rate:9.0%. supervision conditions:None. MFN tariff:5.5%. general tariff:30.0%

 Synonyms

2,5-BIS(TRIFLUOROMETHYL)BENZYL AMINE
4-Fluor-2.6-dibrom-1-hydroxy-benzol
EINECS 206-451-1
MFCD00002317
2,6-dibromo-4-fluoro-phenol
2,6-Dibrom-4-fluor-phenol
2,6-dibromo-4-flurophenol
Phenol,2,6-dibromo-4-fluoro
Phenol, 2,6-dibromo-4-fluoro-
2,6-Dibromo-4-fluorophenol
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