4-chlorobenzenesulfonyl fluoride

Modify Date: 2024-01-10 05:34:14

4-chlorobenzenesulfonyl fluoride Structure
4-chlorobenzenesulfonyl fluoride structure
 Common Name 4-chlorobenzenesulfonyl fluoride
CAS Number 349-89-3 Molecular Weight 194.61100
Density 1.473g/cm3 Boiling Point 236.3ºC at 760 mmHg
Molecular Formula C6H4ClFO2S Melting Point 45-50 ℃
MSDS Chinese USA Flash Point 96.7ºC
Symbol GHS05
GHS05		 Signal Word Danger

 Names

Name 4-chlorobenzenesulfonyl fluoride
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.473g/cm3
Boiling Point 236.3ºC at 760 mmHg
Melting Point 45-50 ℃
Molecular Formula C6H4ClFO2S
Molecular Weight 194.61100
Flash Point 96.7ºC
Exact Mass 193.96000
PSA 42.52000
LogP 3.07900
Index of Refraction 1.525

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DB8943000
CHEMICAL NAME :
Benzenesulfonyl fluoride, p-chloro-
CAS REGISTRY NUMBER :
349-89-3
BEILSTEIN REFERENCE NO. :
2091507
LAST UPDATED :
199709
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C6-H4-Cl-F-O2-S
MOLECULAR WEIGHT :
194.61
WISWESSER LINE NOTATION :
WSFR DG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
56 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#05078

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Hazard Codes C
Safety Phrases 26-36/37/39-45
RIDADR UN3261 8/PGII
RTECS DB8943000

 Synthetic Route

bis(4-chlorophenyl) disulfide structure

bis(4-chlorophe...

CAS#:1142-19-4

~94%

4-chlorobenzenesulfonyl fluoride Structure

4-chlorobenzene...

CAS#:349-89-3
Literature: Kirihara, Masayuki; Naito, Sayuri; Nishimura, Yuki; Ishizuka, Yuki; Iwai, Toshiaki; Takeuchi, Haruka; Ogata, Tomomi; Hanai, Honoka; Kinoshita, Yukari; Kishida, Mari; Yamazaki, Kento; Noguchi, Takuya; Yamashoji, Shiro Tetrahedron, 2014 , vol. 70, # 14 p. 2464 - 2471
p-Chlorothiobenzenesulfonic acid S-(p-chlorophenyl) ester structure

p-Chlorothioben...

CAS#:1146-44-7

~96%

4-chlorobenzenesulfonyl fluoride Structure

4-chlorobenzene...

CAS#:349-89-3
Literature: Kirihara, Masayuki; Naito, Sayuri; Nishimura, Yuki; Ishizuka, Yuki; Iwai, Toshiaki; Takeuchi, Haruka; Ogata, Tomomi; Hanai, Honoka; Kinoshita, Yukari; Kishida, Mari; Yamazaki, Kento; Noguchi, Takuya; Yamashoji, Shiro Tetrahedron, 2014 , vol. 70, # 14 p. 2464 - 2471
bis(4-chlorophenyl) disulfide structure

bis(4-chlorophe...

CAS#:1142-19-4

~9%

p-Chlorothiobenzenesulfonic acid S-(p-chlorophenyl) ester structure

p-Chlorothioben...

CAS#:1146-44-7
4-chlorobenzenesulfonyl fluoride Structure

4-chlorobenzene...

CAS#:349-89-3
Literature: Kirihara, Masayuki; Naito, Sayuri; Nishimura, Yuki; Ishizuka, Yuki; Iwai, Toshiaki; Takeuchi, Haruka; Ogata, Tomomi; Hanai, Honoka; Kinoshita, Yukari; Kishida, Mari; Yamazaki, Kento; Noguchi, Takuya; Yamashoji, Shiro Tetrahedron, 2014 , vol. 70, # 14 p. 2464 - 2471
4-Chlorobenzenesulfonyl chloride structure

4-Chlorobenzene...

CAS#:98-60-2

~63%

4-chlorobenzenesulfonyl fluoride Structure

4-chlorobenzene...

CAS#:349-89-3
Literature: Matesic, Lidia; Wyatt, Naomi A.; Fraser, Benjamin H.; Roberts, Maxine P.; Pham, Tien Q.; Greguric, Ivan Journal of Organic Chemistry, 2013 , vol. 78, # 22 p. 11262 - 11270
Chlorobenzene structure

Chlorobenzene

CAS#:108-90-7

~%

4-chlorobenzenesulfonyl fluoride Structure

4-chlorobenzene...

CAS#:349-89-3
Literature: Kulka Journal of the American Chemical Society, 1950 , vol. 72, p. 1215,1217
4-Chlorobenzenesulfonamide structure

4-Chlorobenzene...

CAS#:98-64-6

~%

4-chlorobenzenesulfonyl fluoride Structure

4-chlorobenzene...

CAS#:349-89-3
Literature: Ivanov, S. N.; Gnedin, B. G. Journal of Organic Chemistry USSR (English Translation), 1981 , vol. 17, p. 1909 - 1914 Zhurnal Organicheskoi Khimii, 1981 , vol. 17, # 10 p. 2142 - 2147

 Synonyms

Benzenesulfonyl fluoride,4-chloro-(9CI)
4-chlorobenzene-1-sulfonyl fluoride
4-Chlor-benzolsulfonylfluorid
Benzenesulfonyl fluoride,4-chloro
4-Chlorophenylsulfonyl fluoride
Benzenesulfonyl fluoride,p-chloro
4-chloro-benzenesulfonyl fluoride
p-chlorobenzene-1-sulfonyl fluoride
p-Chlorobenzenesulfonyl fluoride
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