4-IODO-2,1,3-BENZOTHIADIAZOLE

Modify Date: 2024-01-16 08:55:04

4-IODO-2,1,3-BENZOTHIADIAZOLE Structure
4-IODO-2,1,3-BENZOTHIADIAZOLE structure
Common Name 4-IODO-2,1,3-BENZOTHIADIAZOLE
CAS Number 352018-95-2 Molecular Weight 262.071
Density 2.2±0.1 g/cm3 Boiling Point 298.2±13.0 °C at 760 mmHg
Molecular Formula C6H3IN2S Melting Point 96ºC
MSDS USA Flash Point 134.1±19.8 °C

 Names

Name 4-iodo-2,1,3-benzothiadiazole
Synonym More Synonyms

 Chemical & Physical Properties

Density 2.2±0.1 g/cm3
Boiling Point 298.2±13.0 °C at 760 mmHg
Melting Point 96ºC
Molecular Formula C6H3IN2S
Molecular Weight 262.071
Flash Point 134.1±19.8 °C
Exact Mass 261.906158
PSA 54.02000
LogP 3.01
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.792

 MSDS

Name: 4-Iodo-2 1 3-benzothiadiazole 97% Material Safety Data Sheet
Synonym:
CAS: 352018-95-2
Section 1 - Chemical Product MSDS Name:4-Iodo-2 1 3-benzothiadiazole 97% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
352018-95-2 4-Iodo-2,1,3-benzothiadiazole 97% unlisted
Hazard Symbols: C
Risk Phrases: None Listed.

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 352018-95-2: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: brown
Odor: characteristic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 90 - 92 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H3IN2S
Molecular Weight: 262.07

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen iodide, iodine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 352018-95-2 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
4-Iodo-2,1,3-benzothiadiazole - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 352018-95-2: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 352018-95-2 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 352018-95-2 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes C:Corrosive
Safety Phrases S24/25
HS Code 2934999090

 Synthetic Route

~84%

4-IODO-2,1,3-BENZOTHIADIAZOLE Structure

4-IODO-2,1,3-BE...

CAS#:352018-95-2

Literature: Zimdars, Silvia; Langhals, Heinz; Knochel, Paul Synthesis, 2011 , # 8 art. no. T15911SS, p. 1302 - 1308

 Precursor & DownStream

Precursor  1

DownStream  0

 Customs

HS Code 2934999090
Summary 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

4-Iodobenzo[c][1,2,5]thiadiazole
2,1,3-Benzothiadiazole,4-iodo
2,1,3-Benzothiadiazole, 4-iodo-
4-IODO-2,1,3-BENZOTHIADIAZOLE
4-iodo-[2,1,3]-benzothiadiazole
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